ArticleNature communications2018
Stereoselective photoredox ring-opening polymerization of O-carboxyanhydrides.
Article in Nature communications, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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Who cites it
9 citing papers in PubMed.
- Stereosequence- and topology-controlled synthesis of cyclic polyesters.Nature communications · 2026Article
- Stereoselective Ring-Opening Polymerization of Racemic Dithiolactones Assisted by Non-Classical C─H⋯X Interactions.Angewandte Chemie (International ed. in English) · 2026Article
- Synthetic Polymers for Drug, Gene, and Vaccine Delivery.Polymer science & technology (Washington, D.C.) · 2025Review
- Recent advances in enantioselective ring-opening polymerization and copolymerization.Communications chemistry · 2023Review
- A nanoscale MOF-based heterogeneous catalytic system for the polymerization of N-carboxyanhydrides enables direct routes toward both polypeptides and related hybrid materials.Nature communications · 2023Article
- Bayesian-optimization-assisted discovery of stereoselective aluminum complexes for ring-opening polymerization of racemic lactide.Nature communications · 2023Article
- Photocatalyst-independent photoredox ring-opening polymerization ofChemical science · 2021Article
- Stereoselective gridization and polygridization with centrosymmetric molecular packing.Nature communications · 2020Article
- Living Ring-Opening Polymerization ofFrontiers in chemistry · 2018Review
Corrections and comments
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Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Biodegradable polyesters with various tacticities have been synthesized by means of stereoselective ring-opening polymerization of racemic lactide and β-lactones but with limited side-chain groups. However, stereoselective synthesis of functional polyesters remains challenging from O-carboxyanhydrides that have abundant pendant side-chain functional groups. Herein we report a powerful strategy to synthesize stereoblock polyesters by stereoselective ring-opening polymerization of racemic O-carboxyanhydrides with the use of photoredox Ni/Ir catalysts and a selected Zn complex with an achiral ligand. The obtained stereoblock copolymers are highly isotactic with high molecular weights ( > 70 kDa) and narrow molecular weight distributions (M
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