ArticleProceedings of the National Academy of Sciences of the United States of America2018
Two-dimensional infrared spectroscopy of vibrational polaritons.
Article in Proceedings of the National Academy of Sciences of the United States of America, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 46 papers.
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Who cites it
46 citing papers in PubMed.
- Reservoir Dynamics in Vibrational Polaritons Revealed by Detuning-Dependent Ultrafast Spectroscopy.The journal of physical chemistry letters · 2026Article
- Phase-Resolved Two-Dimensional Infrared Spectroscopy of Solution-Phase Vibrational Polaritons on Gold Antenna Meta-Surfaces.The journal of physical chemistry letters · 2026Article
- Excited State Dynamics of COJournal of the American Chemical Society · 2025Article
- Vibrational weak and strong coupling modify a chemical reaction via cavity-mediated radiative energy transfer.Nature chemistry · 2025Article
- Disentangling collective coupling in vibrational polaritons with double quantum coherence spectroscopy.The Journal of chemical physics · 2024Article
- Optically accessible long-lived electronic biexcitons at room temperature in strongly coupled H- aggregates.Nature communications · 2024Article
- Controlling Plasmonic Catalysis via Strong Coupling with Electromagnetic Resonators.Nano letters · 2024Article
- Extending the Tavis-Cummings model for molecular ensembles-Exploring the effects of dipole self-energies and static dipole moments.The Journal of chemical physics · 2024Article
- Probing the anharmonicity of vibrational polaritons with double-quantum two-dimensional infrared spectroscopy.Nanophotonics (Berlin, Germany) · 2024Article
- Subradiant plasmonic cavities make bright polariton states dark.Nanophotonics (Berlin, Germany) · 2024Article
- The role of IR inactive mode in W(CO)Nanophotonics (Berlin, Germany) · 2024Article
- Ultrafast Spectroscopy under Vibrational Strong Coupling in Diphenylphosphoryl Azide.The journal of physical chemistry. A · 2024Article
- Molecular Polaritons for Chemistry, Photonics and Quantum Technologies.Chemical reviews · 2024Review
- A Quantum Chemistry Approach to Linear Vibro-Polaritonic Infrared Spectra with Perturbative Electron-Photon Correlation.The journal of physical chemistry letters · 2024Article
- The Rise and Current Status of Polaritonic Photochemistry and Photophysics.Chemical reviews · 2023Review
- Theoretical Advances in Polariton Chemistry and Molecular Cavity Quantum Electrodynamics.Chemical reviews · 2023Review
- The role of dephasing for dark state coupling in a molecular Tavis-Cummings model.The Journal of chemical physics · 2023Article
- A path towards single molecule vibrational strong coupling in a Fabry-Pérot microcavity.Chemical science · 2023Article
- Sub-picosecond collapse of molecular polaritons to pure molecular transition in plasmonic photoswitch-nanoantennas.Nature communications · 2023Article
- Molecular and solid-state topological polaritons induced by population imbalance.Nanophotonics (Berlin, Germany) · 2023Article
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9 authors.
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Abstract
We report experimental 2D infrared (2D IR) spectra of coherent light-matter excitations--molecular vibrational polaritons. The application of advanced 2D IR spectroscopy to vibrational polaritons challenges and advances our understanding in both fields. First, the 2D IR spectra of polaritons differ drastically from free uncoupled excitations and a new interpretation is needed. Second, 2D IR uniquely resolves excitation of hybrid light-matter polaritons and unexpected dark states in a state-selective manner, revealing otherwise hidden interactions between them. Moreover, 2D IR signals highlight the impact of molecular anharmonicities which are applicable to virtually all molecular systems. A quantum-mechanical model is developed which incorporates both nuclear and electrical anharmonicities and provides the basis for interpreting this class of 2D IR spectra. This work lays the foundation for investigating phenomena of nonlinear photonics and chemistry of molecular vibrational polaritons which cannot be probed with traditional linear spectroscopy.
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