Evidence map›Paper›PMID 29665681›Full record

ArticleThe Journal of organic chemistry2018

Synthesis of Symmetric and Unsymmetric Secondary Amines from the Ligand-Promoted Ruthenium-Catalyzed Deaminative Coupling Reaction of Primary Amines.

Pandula T Kirinde Arachchige, Hanbin Lee, Chae S Yi

Abstract read
In one paragraph

Article in The Journal of organic chemistry, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Chelation Drives Surface Substitution in Hybrid-MXenes.Angewandte Chemie (International ed. in English) · 2026
    Article
  2. Mild and Functional Group-Tolerant AerobicThe Journal of organic chemistry · 2023
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Pandula T Kirinde ArachchigeDepartment of Chemistry , Marquette University , Milwaukee , Wisconsin 53201-1881 , United States.
Hanbin LeeDepartment of Chemistry , Marquette University , Milwaukee , Wisconsin 53201-1881 , United States.
Chae S YiDepartment of Chemistry , Marquette University , Milwaukee , Wisconsin 53201-1881 , United States.ORCID 0000-0002-4504-1151

Funding

Catalytic Coupling Reactions via C-H and C-N Bond ActivationR15GM109273 · NIGMS · MARQUETTE UNIVERSITY · PI YI, CHAE S · 2014 to 2014
$334k
NIGMS NIH HHS R15 GM109273
6 · The paper itself

Abstract

The catalytic system generated in situ from the tetranuclear Ru-H complex with a catechol ligand (1/L1) was found to be effective for the direct deaminative coupling of two primary amines to form secondary amines. The catalyst 1/L1 was highly chemoselective for promoting the coupling of two different primary amines to afford unsymmetric secondary amines. The analogous coupling of aniline with primary amines formed aryl-substituted secondary amines. The treatment of aniline- d

Indexed as

AminesCatalysisChemistry Techniques, SyntheticLigandsRutheniumStereoisomerismAminesLigandsRuthenium

Identifiers

PMID29665681
PMCPMC5998338

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.