ArticleAngewandte Chemie (International ed. in English)2018
Highly Efficient and Stereoselective Thioallylation of Alkynes: Possible Gold Redox Catalysis with No Need for a Strong Oxidant.
Article in Angewandte Chemie (International ed. in English), 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
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Who cites it
15 citing papers in PubMed, 64 citations in OpenAlex.
- Regiodivergent Gold-Catalyzed Rearrangement-Addition Reactions of Sulfenylated Propargylic Carboxylates with Indoles.Organic letters · 2024Article
- Accessing gold p-acid reactivity under electrochemical anode oxidation (EAO) through oxidation relay.Nature communications · 2023Article
- Accessing Gold π-Acid Reactivity under Electrochemical Anode Oxidation (EAO) through Oxidation Relay.Research square · 2023Article
- Controlling Selectivity in Shuttle Hetero-difunctionalization Reactions: Electrochemical Transfer Halo-thiolation of Alkynes.Angewandte Chemie (International ed. in English) · 2023Article
- Chiral Hemilabile P,N-Ligand-Assisted Gold Redox Catalysis for Enantioselective Alkene Aminoarylation.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Gold(I)-Catalyzed Synthesis of 3-Sulfenyl Pyrroles and Indoles by a Regioselective Annulation of Alkynyl Thioethers.ACS catalysis · 2021Article
- Palladium(II)-assisted activation of thioglycosides.Organic & biomolecular chemistry · 2021Article
- Electrochemical gold redox catalysis for selective oxidative arylation.Green synthesis and catalysis · 2021Article
- Intermolecular Alkene Difunctionalization via Gold-Catalyzed Oxyarylation.Angewandte Chemie (International ed. in English) · 2020Article
- Facilitating Ir-Catalyzed C-H Alkynylation with Electrochemistry: Anodic Oxidation-Induced Reductive Elimination.ACS catalysis · 2020Article
- Hexafluoroisopropanol-Promoted Disulfidation and Diselenation of Alkyne, Alkene, and Allene.Organic letters · 2020Article
- Diazo Activation with Diazonium Salts: Synthesis of Indazole and 1,2,4-Triazole.Organic letters · 2020Article
- Gold Redox Catalysis with a Selenium Cation as a Mild Oxidant.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Facilitating Gold Redox Catalysis with Electrochemistry: An Efficient Chemical-Oxidant-Free Approach.Angewandte Chemie (International ed. in English) · 2019Article
- Gold redox catalysis for cyclization/arylation of allylic oximes: synthesis of isoxazoline derivatives.Chemical communications (Cambridge, England) · 2019Article
Corrections and comments
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Authors and funding
7 authors at 3 institutions in 1 country.
Funding
Abstract
Stereoselective thioallylation of alkynes under possible gold redox catalysis was accomplished with high efficiency (as low as 0.1 % catalyst loading, up to 99 % yield) and broad substrate scope (various alkynes, inter- and intramolecular fashion). The gold(I) catalyst acts as both a π-acid for alkyne activation and a redox catalyst for Au
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.