ReviewACS catalysis2018
Supramolecular Approaches To Control Activity and Selectivity in Hydroformylation Catalysis.
Review in ACS catalysis, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
What it found
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Who cites it
20 citing papers in PubMed.
- Self-Assembly of a Customizable Library of Nickel Trifluoromethylation Catalysts via Selective C─F and C─O Bond Cleavage.Angewandte Chemie (International ed. in English) · 2025Article
- Boosting Hydroformylation via Reactant Enrichment in Covalent Triazine Frameworks with Atomically Dispersed Rh.Materials (Basel, Switzerland) · 2025Article
- A Resorcin[4]arene-Based Phosphite-Phosphine Ligand for the Branched-Selective Hydroformylation of Alkyl Alkenes.ACS catalysis · 2024Article
- P(V)-Promoted Rh-Catalyzed Highly Regioselective Hydroformylation of Styrenes under Mild Conditions.Molecules (Basel, Switzerland) · 2024Article
- Substrate scope driven optimization of an encapsulated hydroformylation catalyst.Catalysis science & technology · 2024Article
- Monomeric, Oligomeric, Polymeric, and Supramolecular Cyclodextrins as Catalysts for Green Chemistry.Research (Washington, D.C.) · 2024Article
- A substrate descriptor based approach for the prediction and understanding of the regioselectivity in caged catalyzed hydroformylation.Faraday discussions · 2023Article
- Structural and dimensional control of porphyrin capsules using Group 15 tris(3-pyridyl) linkers.Chemical science · 2023Article
- Single-atom catalysts for hydroformylation of olefins.iScience · 2023Review
- Sustainable Wacker-Type Oxidations.Angewandte Chemie (International ed. in English) · 2022Review
- Just Add Water: Modulating the Structure-Derived Acidity of Catalytic Hexameric Resorcinarene Capsules.Journal of the American Chemical Society · 2021Article
- Phosphorus coordinated Rh single-atom sites on nanodiamond as highly regioselective catalyst for hydroformylation of olefins.Nature communications · 2021Article
- Base-Catalyzed, Solvent-Free Synthesis of Rigid V-Shaped Epoxydibenzo[The Journal of organic chemistry · 2021Article
- A domino reaction for generating β-aryl aldehydes from alkynes by substrate recognition catalysis.Nature communications · 2019Article
- Hydrogen Bond Directed ortho-Selective C-H Borylation of Secondary Aromatic Amides.Angewandte Chemie (International ed. in English) · 2019Article
- Effector responsive hydroformylation catalysis.Chemical science · 2019Article
- A Supramolecular Strategy for Selective Catalytic Hydrogenation Independent of Remote Chain Length.Journal of the American Chemical Society · 2019Article
- Bio-inspired creation of heterogeneous reaction vessels via polymerization of supramolecular ion pair.Nature communications · 2019Article
- Gold-catalyzed Cycloisomerization Reactions within Guanidinium MChemCatChem · 2019Article
- Cofactor Controlled Encapsulation of a Rhodium Hydroformylation Catalyst.Angewandte Chemie (International ed. in English) · 2019Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The hydroformylation reaction is one of the most intensively explored reactions in the field of homogeneous transition metal catalysis, and many industrial applications are known. However, this atom economical reaction has not been used to its full potential, as many selectivity issues have not been solved. Traditionally, the selectivity is controlled by the ligand that is coordinated to the active metal center. Recently, supramolecular strategies have been demonstrated to provide powerful complementary tools to control activity and selectivity in hydroformylation reactions. In this review, we will highlight these supramolecular strategies. We have organized this paper in sections in which we describe the use of supramolecular bidentate ligands, substrate preorganization by interactions between the substrate and functional groups of the ligands, and hydroformylation catalysis in molecular cages.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.