Evidence map›Paper›PMID 29654233›Full record

ArticleNature communications2018

Simultaneous complementary photoswitching of hemithioindigo tweezers for dynamic guest relocalization.

Sandra Wiedbrauk, Thomas Bartelmann, Stefan Thumser, Peter Mayer, Henry Dube

Abstract read
In one paragraph

Article in Nature communications, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.

0numbers the graph read from it
0cells of the map it votes in
20citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

20 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Article
  5. Switchable molecular tweezers: design and applications.Beilstein journal of organic chemistry · 2024
    Review
  6. Article
  7. Article
  8. Review
  9. Article
  10. Photopharmacology of Antimitotic Agents.International journal of molecular sciences · 2022
    Review
  11. Molecular photoswitches in aqueous environments.Chemical Society reviews · 2021
    Review
  12. Article
  13. Article
  14. Article
  15. Article
  16. Article
  17. Reversible Photoswitching of Isolated Ionic Hemiindigos with Visible Light.Chemphyschem : a European journal of chemical physics and physical chemistry · 2020
    Article
  18. Active and Unidirectional Acceleration of Biaryl Rotation by a Molecular Motor.Angewandte Chemie (International ed. in English) · 2020
    Article
  19. Article
  20. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Sandra WiedbraukDepartment of Chemistry, Ludwig-Maximilians-Universität München, Butenandtstrasse 5-13, München, 81377, Germany.
Thomas BartelmannDepartment of Chemistry, Ludwig-Maximilians-Universität München, Butenandtstrasse 5-13, München, 81377, Germany.
Stefan ThumserDepartment of Chemistry, Ludwig-Maximilians-Universität München, Butenandtstrasse 5-13, München, 81377, Germany.
Peter MayerDepartment of Chemistry, Ludwig-Maximilians-Universität München, Butenandtstrasse 5-13, München, 81377, Germany.
Henry DubeDepartment of Chemistry, Ludwig-Maximilians-Universität München, Butenandtstrasse 5-13, München, 81377, Germany. henry.dube@cup.uni-muenchen.de.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Remote control of complex molecular behavior and function is one key problem in modern chemistry. Using light signaling for this purpose has many advantages, however the integration of different photo processes into a wholesome yet complex system is highly challenging. Here we report an alternative approach to increase complexity of light control-simultaneous complementary photoswitching-in which spectral overlap is used as an advantage to drastically reduce the signaling needed for controlling multipart supramolecular assemblies. Two photoswitchable molecular tweezers respond to the same light signals with opposite changes in their binding affinities. In this way the configuration of two host tweezers and ultimately the dynamic relocation of a guest molecule can be trigged by only one signal reversibly in the same solution. This approach should provide a powerful tool for the construction of sophisticated, integrated, and multi-responsive smart molecular systems in any application driven field of chemistry.

Identifiers

PMID29654233
PMCPMC5899155

What OpenQuestion holds

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LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.