Evidence map›Paper›PMID 29632331›Full record

ArticleNature communications2018

Quantitative 3D determination of self-assembled structures on nanoparticles using small angle neutron scattering.

Zhi Luo, Domenico Marson, Quy K Ong, Anna Loiudice, Joachim Kohlbrecher, Aurel Radulescu, Anwen Krause-Heuer, Tamim Darwish, Sandor Balog, Raffaella Buonsanti and 3 more

Abstract read
In one paragraph

Article in Nature communications, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 19 papers.

0numbers the graph read from it
0cells of the map it votes in
19citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

19 citing papers in PubMed.

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  8. Updates inJournal of applied crystallography · 2022
    Article
  9. Article
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  12. Dependence of the Nanoscale Composite Morphology of FeMolecules (Basel, Switzerland) · 2021
    Article
  13. Article
  14. Article
  15. Determination and evaluation of the nonadditivity in wetting of molecularly heterogeneous surfaces.Proceedings of the National Academy of Sciences of the United States of America · 2019
    Article
  16. Article
  17. Article
  18. Article
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

13 authors.

Zhi LuoInstitute of Materials, École Polytechnique Fédérale de Lausanne, 1015, Lausanne, Switzerland.
Domenico MarsonDepartment of Engineering and Architecture and INSTM Trieste Unit, University of Trieste, 34127, Trieste, Italy.ORCID http://orcid.org/0000-0003-1839-9868
Quy K OngInstitute of Materials, École Polytechnique Fédérale de Lausanne, 1015, Lausanne, Switzerland.
Anna LoiudiceInstitute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne, 1015, Lausanne, Switzerland.
Joachim KohlbrecherLaboratory for Neutron Scattering and Imaging, Paul-Scherrer Institute, 5232, Villigen, Switzerland.
Aurel RadulescuJülich Center for Neutron Science, JCNS at Heinz Maier-Leibnitz Zentrum, Forschungszentrum Jülich GmbH, 85747, Garching, Germany.
Anwen Krause-HeuerThe National Deuteration Facility, Australian Nuclear Science and Technology Organisation, Kirrawee DC, NSW, 2232, Australia.
Tamim DarwishThe National Deuteration Facility, Australian Nuclear Science and Technology Organisation, Kirrawee DC, NSW, 2232, Australia.
Sandor BalogAdolphe Merkle Institute, University of Fribourg, 1700, Fribourg, Switzerland.
Raffaella BuonsantiInstitute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne, 1015, Lausanne, Switzerland.
Dmitri I SvergunEuropean Molecular Biology Laboratory, Hamburg Unit, EMBL c/o DESY, 22603, Hamburg, Germany.
Paola PosoccoDepartment of Engineering and Architecture and INSTM Trieste Unit, University of Trieste, 34127, Trieste, Italy.
Francesco StellacciInstitute of Materials, École Polytechnique Fédérale de Lausanne, 1015, Lausanne, Switzerland. francesco.stellacci@epfl.ch.ORCID http://orcid.org/0000-0003-4635-6080

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The ligand shell (LS) determines a number of nanoparticles' properties. Nanoparticles' cores can be accurately characterized; yet the structure of the LS, when composed of mixture of molecules, can be described only qualitatively (e.g., patchy, Janus, and random). Here we show that quantitative description of the LS' morphology of monodisperse nanoparticles can be obtained using small-angle neutron scattering (SANS), measured at multiple contrasts, achieved by either ligand or solvent deuteration. Three-dimensional models of the nanoparticles' core and LS are generated using an ab initio reconstruction method. Characteristic length scales extracted from the models are compared with simulations. We also characterize the evolution of the LS upon thermal annealing, and investigate the LS morphology of mixed-ligand copper and silver nanoparticles as well as gold nanoparticles coated with ternary mixtures. Our results suggest that SANS combined with multiphase modeling is a versatile approach for the characterization of nanoparticles' LS.

Identifiers

PMID29632331
PMCPMC5890256

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.