ArticleJournal of the American Chemical Society2018
C(alkenyl)-H Activation via Six-Membered Palladacycles: Catalytic 1,3-Diene Synthesis.
Article in Journal of the American Chemical Society, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 32 papers.
What it found
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Who cites it
32 citing papers in PubMed.
- Catalytic Functionalization of Unactivated π-Bonds Enabled by Bidentate Directing Auxiliaries.Angewandte Chemie (International ed. in English) · 2026Review
- N,N- and N,O-Bidentate-Chelation-Assisted Alkenyl C-H Functionalization.Molecules (Basel, Switzerland) · 2025Review
- Directed copper-catalyzed C-H functionalization of unactivated olefins with azodicarbonamide compounds.RSC advances · 2024Article
- Pd-Catalyzed C(spThe Journal of organic chemistry · 2024Article
- Review
- Remote-carbonyl-directed sequential Heck/isomerization/C(spNature communications · 2024Article
- Ru(phen)ChemistryOpen · 2023Article
- Pd(ii)-catalyzed β- and γ-C-(spChemical science · 2023Article
- Iron-Catalyzed Cross-Coupling of α-Allenyl Esters with Grignard Reagents for the Synthesis of 1,3-Dienes.Organic letters · 2023Article
- Regio- and Stereoselective 1,2-Oxyhalogenation of Non-Conjugated Alkynes via Directed Nucleopalladation: Catalytic Access to Tetrasubstituted Alkenes.Angewandte Chemie (International ed. in English) · 2022Article
- Picolinamides and Iodoalkynes Enable Palladium-Catalyzed syn-Aminoalkynylation of Di- and Trisubstituted Alkenes to Give Pyrrolidines.Angewandte Chemie (International ed. in English) · 2022Article
- PdAngewandte Chemie (International ed. in English) · 2022Article
- Intermolecular Photocatalytic Chemo-, Stereo- and Regioselective Thiol-Yne-Ene Coupling Reaction.Angewandte Chemie (International ed. in English) · 2022Article
- Mapping Ambiphile Reactivity Trends in the Anti-(Hetero)annulation of Non-Conjugated Alkenes via PdAngewandte Chemie (International ed. in English) · 2022Article
- Phosphine-catalyzed divergent domino processes between γ-substituted allenoates and carbonyl-activated alkenes.Chemical science · 2022Article
- A Dual CuH- and Pd-Catalyzed Stereoselective Synthesis of Highly Substituted 1,3-Dienes.Organic letters · 2021Article
- Pd/Cu-Catalyzed amide-enabled selectivity-reversed borocarbonylation of unactivated alkenes.Chemical science · 2021Article
- Modular synthesis of non-conjugatedTetrahedron · 2021Article
- A Study of an 8-Aminoquinoline-Directed C(spThe Journal of organic chemistry · 2021Article
- Palladium/norbornene-catalyzed distal alkenyl C-H arylation and alkylation of cis-olefins.Tetrahedron · 2021Article
Corrections and comments
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Authors and funding
6 authors.
Funding
Abstract
A catalytic method to prepare highly substituted 1,3-dienes from two different alkenes is described using a directed, palladium(II)-mediated C(alkenyl)-H activation strategy. The transformation exhibits broad scope across three synthetically useful substrate classes masked with suitable bidentate auxiliaries (4-pentenoic acids, allylic alcohols, and bishomoallylic amines) and tolerates internal nonconjugated alkenes, which have traditionally been a challenging class of substrates in this type of chemistry. Catalytic turnover is enabled by either MnO
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