ArticleChemical science2018
Cage-templated synthesis of highly stable palladium nanoparticles and their catalytic activities in Suzuki-Miyaura coupling.
Article in Chemical science, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 19 papers.
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Who cites it
19 citing papers in PubMed.
- Ionic organic molecular cage-supported Pd nanoparticles for aqueous Suzuki-Miyaura coupling.Chemical communications (Cambridge, England) · 2026Article
- Beyond symmetric self-assembly and effective molarity: unlocking functional enzyme mimics with robust organic cages.Beilstein journal of organic chemistry · 2025Article
- Programmable synthesis of organic cages with reduced symmetry.Chemical science · 2024Article
- Dynamic covalent self-assembly and self-sorting processes in the formation of imine-based macrocycles and macrobicyclic cages.Chemical science · 2023Article
- Porous Organic Cages.Chemical reviews · 2023Review
- Post-Synthetic Modification of a Porous Hydrocarbon Cage to Give a Discrete CoChemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- N-heterocyclic carbene-stabilized metal nanoparticles within porous organic cages for catalytic application.National science review · 2022Article
- Chiral proline-substituted porous organic cages in asymmetric organocatalysis.Chemical science · 2022Article
- Confinement synthesis in porous molecule-based materials: a new opportunity for ultrafine nanostructures.Chemical science · 2022Review
- A coordination cage hosting ultrafine and highly catalytically active gold nanoparticles.Chemical science · 2022Article
- Calcium hydroxyapatite nanoparticles as a reinforcement filler in dental resin nanocomposite.Journal of materials science. Materials in medicine · 2021Article
- Hollow and highly diastereoselective face-rotating polyhedra constructed through rationally engineered facial units.Chemical science · 2021Article
- Isoreticular Crystallization of Highly Porous Cubic Covalent Organic Cage Compounds*.Angewandte Chemie (International ed. in English) · 2021Article
- Endohedral Hydrogen Bonding Templates the Formation of a Highly Strained Covalent Organic Cage Compound*.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- An Active Catalyst System Based on Pd (0) and a Phosphine-Based Bulky Ligand for the Synthesis of Thiophene-Containing Conjugated Polymers.Frontiers in chemistry · 2021Article
- Cavitand and Molecular Cage-Based Porous Organic Polymers.ACS omega · 2020Review
- Cyclodextrin polymer networks decorated with subnanometer metal nanoparticles for high-performance low-temperature catalysis.Science advances · 2019Article
- Synthesis of a Large, Shape-Flexible, Solvatomorphic Porous Organic Cage.Crystal growth & design · 2019Article
- Core-Shell Crystals of Porous Organic Cages.Angewandte Chemie (International ed. in English) · 2018Article
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Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
We report the controlled synthesis of small palladium nanoparticles (PdNPs) with narrow particle size distribution (1.8 ± 0.2 nm) using an organic molecular cage as a template. The well-defined cage structure and thioether anchoring groups inside the cavity are critical for the formation of narrowly distributed PdNPs, offering a confined organic molecular environment and guiding PdNP nucleation and growth. The resulting encapsulated PdNPs are resistant to agglomeration and stable in solution exposed to air at room temperature. When provided with a protective cage shell with minimum surface coverage, such PdNPs are capable of catalyzing organic reactions, showing high catalytic activity in Suzuki-Miyaura coupling reactions.
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Registered trials
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