ArticleChemical science2018
Direct sulfonylation of anilines mediated by visible light.
Article in Chemical science, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
What it found
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
12 citing papers in PubMed.
- Electrochemical Sulfonylation in Deep Eutectic Solvents Enables the Sustainable Synthesis of 2-Quinoline Sulfones.ChemSusChem · 2025Article
- Red-Light-Driven C(spJournal of the American Chemical Society · 2025Article
- Streamlining SuFEx Inhibitor Development: A Unified Approach Using Photolabile and Orthogonal Sulfinate Protecting Groups.Angewandte Chemie (International ed. in English) · 2025Article
- Remote Sulfonylation of Anilines with Sodium Sulfifinates Using Biomass-Derived Copper Catalyst.Molecules (Basel, Switzerland) · 2024Article
- Visible-light-mediated sulfonylation of anilines with sulfonyl fluorides.Frontiers in chemistry · 2023Article
- Determination of Aniline in Soil by ASE/GC-MS.Molecules (Basel, Switzerland) · 2022Article
- Photons or Electrons? A Critical Comparison of Electrochemistry and Photoredox Catalysis for Organic Synthesis.Chemical reviews · 2022Review
- Divergent reactivity of sulfinates with pyridinium salts based on one-Chemical science · 2021Article
- Synthesis and applications of sodium sulfinates (RSORSC advances · 2021Review
- Bond-Forming and -Breaking Reactions at Sulfur(IV): Sulfoxides, Sulfonium Salts, Sulfur Ylides, and Sulfinate Salts.Chemical reviews · 2019Article
- Photoredox-catalyzed branch-selective pyridylation of alkenes for the expedient synthesis of Triprolidine.Nature communications · 2019Article
- The hydrogen atom transfer reactivity of sulfinic acids.Chemical science · 2018Article
Corrections and comments
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Authors and funding
15 authors.
Funding
Abstract
Sulfones feature prominently in biologically active molecules and are key functional groups for organic synthesis. We report a mild, photoredox-catalyzed reaction for sulfonylation of aniline derivatives with sulfinate salts, and demonstrate the utility of the method by the late-stage functionalization of drugs. Key features of the method are the straightforward generation of sulfonyl radicals from bench-stable sulfinate salts and the use of simple aniline derivatives as convenient readily available coupling partners.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.