ArticleChemical science2018
Selective lithium ion recognition in self-assembled columnar liquid crystals based on a lithium receptor.
Article in Chemical science, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
1 citing paper in PubMed, 42 citations in OpenAlex.
- 4-Phosphoryl Pyrazolones for Highly Selective Lithium Separation from Alkali Metal Ions.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
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Authors and funding
3 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Lithium is recognized as being significantly important due to its various applications in different areas especially in energy technology. In the present study, self-assembled nanostructured liquid-crystalline (LC) materials, that selectively bind lithium cations, have been developed for the first time. Wedge-shaped crown ether derivatives bearing dibenzo-14-crown-4 (DB14C4) or 12-crown-4 moieties are able to act as LC lithium-selective receptors. We have found that complexation of these receptors with lithium perchlorate induces liquid-crystalline columnar phases, while sodium perchlorate is immiscible with both receptors. Remarkably, a receptor consisting of DB14C4 as an effective lithium-selective ligand exhibits high selectivity for LiCl over NaCl, KCl, RbCl and CsCl. The lithium selectivity was demonstrated and investigated by
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Registered trials
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