ArticleChemical science2018
Tracking the picosecond deactivation dynamics of a photoexcited iron carbene complex by time-resolved X-ray scattering.
Article in Chemical science, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 25 papers.
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Who cites it
25 citing papers in PubMed.
- A new reference for changes in X-ray scattering from water due to temperature changes at ambient conditions.Journal of synchrotron radiation · 2026Article
- Ultrafast Population and Structural Dynamics of a Ni-Bipyridine Photoredox Catalyst Reveal a Significant Deactivation Pathway.The journal of physical chemistry letters · 2026Article
- Structure and ultrafast dynamics of tri-nuclear Ag-/Tl-PtStructural dynamics (Melville, N.Y.) · 2025Article
- Simulation of Ultrafast Excited-State Dynamics in Fe(II) Complexes: Assessment of Electronic Structure Descriptions.Journal of chemical theory and computation · 2025Article
- Ultrafast Two-Color X-Ray Emission Spectroscopy Reveals Excited State Landscape in a Base Metal Dyad.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Structure and spin of the low- and high-spin states of FeStructural dynamics (Melville, N.Y.) · 2024Article
- Multifaceted Deactivation Dynamics of Fe(II)The journal of physical chemistry. A · 2023Article
- Projection to extract the perpendicular component (PEPC) method for extracting kinetics from time-resolved data.Structural dynamics (Melville, N.Y.) · 2023Article
- Can range-separated functionals be optimally tuned to predict spectra and excited state dynamics in photoactive iron complexes?Chemical science · 2023Article
- Branching mechanism of photoswitching in an Fe(II) polypyridyl complex explained by full singlet-triplet-quintet dynamics.Communications chemistry · 2023Article
- Pseudo-Octahedral Iron(II) Complexes with Near-Degenerate Charge Transfer and Ligand Field States at the Franck-Condon Geometry.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Reaction dynamics studiedChemical science · 2022Review
- Resolving Femtosecond Solvent Reorganization Dynamics in an Iron Complex by Nonadiabatic Dynamics Simulations.Journal of the American Chemical Society · 2022Article
- Toward Simulation of Fe(II) Low-Spin → High-Spin Photoswitching by Synergistic Spin-Vibronic Dynamics.Journal of chemical theory and computation · 2022Article
- Resonant X-ray photo-oxidation of light-harvesting iron (II/III) N-heterocyclic carbene complexes.Scientific reports · 2021Article
- Filming ultrafast roaming-mediated isomerization of bismuth triiodide in solution.Nature communications · 2021Article
- Femtosecond Charge Density Modulations in Photoexcited CuWOThe journal of physical chemistry. C, Nanomaterials and interfaces · 2021Article
- Intersystem Crossing and Triplet Dynamics in an Iron(II) N-Heterocyclic Carbene Photosensitizer.Inorganic chemistry · 2020Article
- Origin of core-to-core x-ray emission spectroscopy sensitivity to structural dynamics.Structural dynamics (Melville, N.Y.) · 2020Article
- Integrating solvation shell structure in experimentally driven molecular dynamics using x-ray solution scattering data.The Journal of chemical physics · 2020Article
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Authors and funding
15 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Recent years have seen the development of new iron-centered N-heterocyclic carbene (NHC) complexes for solar energy applications. Compared to typical ligand systems, the NHC ligands provide Fe complexes with longer-lived metal-to-ligand charge transfer (MLCT) states. This increased lifetime is ascribed to strong ligand field splitting provided by the NHC ligands that raises the energy levels of the metal centered (MC) states and therefore reduces the deactivation efficiency of MLCT states. Among currently known NHC systems, [Fe(btbip)
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