ArticleChemical science2018
Polarisation effects on the solvation properties of alcohols.
Article in Chemical science, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed.
- Matrix Isolation and Solvation of the Benzonitrile Radical Anion.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Negative cooperativity in the formation of H-bond networks involving primary anilines.Chemical science · 2024Article
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- Antioxidant and Antibacterial Activities of the Leaf and Stem Extracts ofPlants (Basel, Switzerland) · 2023Article
- Stability of mesoporous silica using ricinoleic methyl ester as a template with the addition of HCl and application of CdRSC advances · 2023Article
- Enzyme-like polyene cyclizations catalyzed by dynamic, self-assembled, supramolecular fluoro alcohol-amine clusters.Nature communications · 2023Article
- Quantitative Measurement of Cooperativity in H-Bonded Networks.Journal of the American Chemical Society · 2022Article
- The Global Polarity of Alcoholic Solvents and Water - Importance of the Collectively Acting Factors Density, Refractive Index and Hydrogen Bonding Forces.ChemistryOpen · 2022Article
- An empirical model for solvation based on surface site interaction points.Chemical science · 2021Article
- Regio- and stereoselective thiocyanatothiolation of alkynes and alkenes by using NHRSC advances · 2020Article
- Functional group interaction profiles: a general treatment of solvent effects on non-covalent interactions.Chemical science · 2020Article
- Article
Corrections and comments
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Alcohol solvents are significantly more polar than expected based on the measured H-bonding properties of monomeric alcohols in dilute solution. Self-association of alcohols leads to formation of cyclic aggregates and linear polymeric chains that have a different polarity from the alcohol monomer. Cyclic aggregates are less polar than the monomer, and the chain ends of linear polymers are more polar. The solvation properties of alcohols therefore depend on the interplay of these self-association equilibria and the equilibria involving interactions with solutes. Twenty-one different molecular recognition probes of varying polarity were used to probe the solvation properties of alkane-alcohol mixtures across a wide range of different solvent compositions. The results allow dissection of the complex equilibria present in these systems. Formation of a H-bond between two alcohol molecules leads to polarisation of the hydroxyl groups, resulting in an increase in binding affinity for subsequent interactions with the unbound donor and acceptor sites. The H-bond donor parameter (
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.