ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2018
Stimuli-Directed Dynamic Reconfiguration in Self-Organized Helical Superstructures Enabled by Chemical Kinetics of Chiral Molecular Motors.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed.
- High-Contrast Handedness Inversion in Circularly Polarized Organic Ultralong Phosphorescence Enabled by an Antagonistic Chirality-Offset Helical Superstructure.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Quadruple Helix Inversions of Liquid Crystals Orchestrated by Direct Chirality Transmission of an Intrinsically Chiral Light-Driven Molecular Machine.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- New buffer systems for photopainting of single biomolecules.RSC applied interfaces · 2024Article
- Motorized Macrocycle: A Photo-responsive Host with Switchable and Stereoselective Guest Recognition.Angewandte Chemie (International ed. in English) · 2021Article
- 3D Chiral Photonic Nanostructures Based on Blue-Phase Liquid Crystals.Small science · 2021Article
- Reversible Thermochromic Photonic Coatings with a Protective Topcoat.ACS applied materials & interfaces · 2021Article
- Atomically precise nanoclusters with reversible isomeric transformation for rotary nanomotors.Nature communications · 2020Article
- An Optical Steam Sterilization Sensor Based On a Dual-Responsive Supramolecular Cross-Linked Photonic Polymer.ACS applied materials & interfaces · 2020Article
- Static and Dynamic Control of Fingerprint Landscapes of Liquid Crystal Network Coatings.ACS applied materials & interfaces · 2020Article
- Exploration of immobilization conditions of cellulosic lyotropic liquid crystals in monomeric solvents byRSC advances · 2018Article
- Stimuli-Directed Dynamic Reconfiguration in Self-Organized Helical Superstructures Enabled by Chemical Kinetics of Chiral Molecular Motors.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2018Article
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Authors and funding
9 authors.
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Abstract
Dynamic controllability of self-organized helical superstructures in spatial dimensions is a key step to promote bottom-up artificial nanoarchitectures and functional devices for diverse applications in a variety of areas. Here, a light-driven chiral overcrowded alkene molecular motor with rod-like substituent is designed and synthesized, and its thermal isomerization reaction exhibits an increasing structural entropy effect on chemical kinetic analysis in anisotropic achiral liquid crystal host than that in isotropic organic liquid. Interestingly, the stimuli-directed angular orientation motion of helical axes in the self-organized helical superstructures doped with the chiral motors enables the dynamic reconfiguration between the planar (thermostationary) and focal conic (photostationary) states. The reversible micromorphology deformation processes are compatible with the free energy fluctuation of self-organized helical superstructures and the chemical kinetics of chiral motors under different conditions. Furthermore, stimuli-directed reversible nonmechanical beam steering is achieved in dynamic hidden periodic photopatterns with reconfigurable attributes prerecorded with a corresponding photomask and photoinduced polymerization.
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