Evidence map›Paper›PMID 29619197›Full record

ArticleChemical science2017

Unveiling the role of boroxines in metal-free carbon-carbon homologations using diazo compounds and boronic acids.

Claudio Bomio, Mikhail A Kabeshov, Arthur R Lit, Shing-Hing Lau, Janna Ehlert, Claudio Battilocchio, Steven V Ley

Abstract read
In one paragraph

Article in Chemical science, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.

0numbers the graph read from it
0cells of the map it votes in
8citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

8 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. ACS catalysis · 2021
    Article
  5. Exploring benzylicChemical science · 2021
    Article
  6. Article
  7. Article
  8. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Claudio BomioDepartment of Chemistry , University of Cambridge , Lensfield Road , Cambridge CB21EW , UK . Email: svl1000@cam.ac.uk ; http://www.leygroup.ch.cam.ac.uk.ORCID 0000-0002-6286-1418
Mikhail A KabeshovDepartment of Chemistry , University of Cambridge , Lensfield Road , Cambridge CB21EW , UK . Email: svl1000@cam.ac.uk ; http://www.leygroup.ch.cam.ac.uk.
Arthur R LitDepartment of Chemistry , University of Cambridge , Lensfield Road , Cambridge CB21EW , UK . Email: svl1000@cam.ac.uk ; http://www.leygroup.ch.cam.ac.uk.
Shing-Hing LauDepartment of Chemistry , University of Cambridge , Lensfield Road , Cambridge CB21EW , UK . Email: svl1000@cam.ac.uk ; http://www.leygroup.ch.cam.ac.uk.ORCID 0000-0001-6967-6576
Janna EhlertDepartment of Chemistry , University of Cambridge , Lensfield Road , Cambridge CB21EW , UK . Email: svl1000@cam.ac.uk ; http://www.leygroup.ch.cam.ac.uk.
Claudio BattilocchioDepartment of Chemistry , University of Cambridge , Lensfield Road , Cambridge CB21EW , UK . Email: svl1000@cam.ac.uk ; http://www.leygroup.ch.cam.ac.uk.ORCID 0000-0002-4601-8527
Steven V LeyDepartment of Chemistry , University of Cambridge , Lensfield Road , Cambridge CB21EW , UK . Email: svl1000@cam.ac.uk ; http://www.leygroup.ch.cam.ac.uk.ORCID 0000-0002-7816-0042

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

By means of computational and experimental mechanistic studies the fundamental role of boroxines in the reaction between diazo compounds and boronic acids was elucidated. Consequently, a selective metal-free carbon-carbon homologation of aryl and vinyl boroxines using TMSCHN

Identifiers

PMID29619197
PMCPMC5859889

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.