ArticleChemical science2017
Abnormal room temperature phosphorescence of purely organic boron-containing compounds: the relationship between the emissive behaviorand the molecular packing, and the potential related applications.
Article in Chemical science, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 28 papers.
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Who cites it
28 citing papers in PubMed, 226 citations in OpenAlex.
- Easily Accessible and Up-Scalable Aliphatic Bis-Formamides with Afterglow Luminescence: Photoluminescence Properties and Applications.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Ultralong organic room-temperature phosphorescence of tetraphenyleneChemical science · 2026Article
- Unveiling the Evolution of Afterglow in Diboraanthracene Scaffolds: From Thermally Activated Delayed Fluorescence to Room-Temperature Phosphorescence.Journal of the American Chemical Society · 2025Article
- Organic room temperature phosphorescence co-crystal with reversible acid/base stimulus response.Smart molecules : open access · 2025Article
- Breaking Kasha's rule for photoswitchable reactive oxygen species generation in carbonylated carbon nitride.National science review · 2025Article
- Accurately adjusted phenothiazine conformations: reversible conformation transformation at room temperature and self-recoverable stimuli-responsive phosphorescence.Light, science & applications · 2025Article
- The Current Advances in Design Strategy (Indirect Strategy and Direct Strategy) for Type-I Photosensitizers.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Review
- Organic Room Temperature Phosphorescence from BN-Substituted Xanthene Derivatives.Angewandte Chemie (International ed. in English) · 2025Article
- Photocured room temperature phosphorescent materials from lignosulfonate.Nature communications · 2024Article
- Metal ion-manipulated afterglow on rhodamine 6G derivative-doped room-temperature phosphorescent PVA films.Frontiers in chemistry · 2024Article
- Construction of room temperature phosphorescent materials with ultralong lifetime by in-situ derivation strategy.Nature communications · 2023Article
- Supramolecular glasses with color-tunable circularly polarized afterglow through evaporation-induced self-assembly of chiral metal-organic complexes.Nature communications · 2023Article
- Aggregation-Induced Dual Phosphorescence from (o-Bromophenyl)-Bis(2,6-Dimethylphenyl)Borane at Room Temperature.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Crystallization induced room-temperature phosphorescence and chiral photoluminescence properties of phosphoramides.Chemical science · 2022Article
- Green Synthesis of Phosphorescent Carbon Dots for Anticounterfeiting and Information Encryption.Sensors (Basel, Switzerland) · 2022Article
- Ultralong phosphorescence cellulose with excellent anti-bacterial, water-resistant and ease-to-process performance.Nature communications · 2022Article
- Molecular-Level Understanding of Dual-RTP via Host-Sensitized Multiple Triplet-to-Triplet Energy Transfers and Data Security Application.ACS omega · 2022Article
- Completely aqueous processable stimulus responsive organic room temperature phosphorescence materials with tunable afterglow color.Nature communications · 2022Article
- Rational design of pyrrole derivatives with aggregation-induced phosphorescence characteristics for time-resolved and two-photon luminescence imaging.Nature communications · 2021Article
- Efficient and organic host-guest room-temperature phosphorescence: tunable triplet-singlet crossing and theoretical calculations for molecular packing.Chemical science · 2021Article
Corrections and comments
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Authors and funding
9 authors at 2 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Purely organic materials with the characteristic of room-temperature phosphorescence (RTP) under ambient conditions demonstrate potential benefits in advanced optoelectronic applications. Exploration of versatile and efficient RTP compounds with low prices is full of challenges due to the slow intersystem crossing process and ultrafast deactivation of the active excited states of organic compounds. Here, a series of boron-containing phosphors were found to present RTP with long-lived lifetimes. Among these commercially available and cheap compounds, (4-methoxyphenyl)boronic acid (PBA-MeO) exhibits long-lived RTP, with a lifetime of 2.24 s, which is among the longest lifetimes of single-component small molecules. Our extensive experiments illustrate that both a rigid conformation and expanded conjugation induced by molecular alignment contribute to the persistent RTP. Because of strong intermolecular interactions
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.