ArticleInorganic chemistry2018
Uncoupled Redox-Inactive Lewis Acids in the Secondary Coordination Sphere Entice Ligand-Based Nitrite Reduction.
Article in Inorganic chemistry, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed.
- Article
- Unveiling an {FeNO}Journal of the American Chemical Society · 2026Article
- Remote Positioning of Cations Tunes Catalytic Fe-Mediated Nitrogen Fixation Selectivity for Hydrazine Instead of Ammonia in Protic Media.Angewandte Chemie (International ed. in English) · 2026Article
- Article
- Selective Stepwise Reduction of Nitrate and Nitrite to Dinitrogen or Ammonia.Journal of the American Chemical Society · 2025Article
- Modulation of the Bonding between Copper and a Redox-Active Ligand by Hydrogen Bonds and Its Effect on Electronic Coupling and Spin States.Journal of the American Chemical Society · 2024Article
- Coordinatively Unsaturated Metallates of Cobalt(II), Nickel(II), and Zinc(II) Guarded by a Rigid and Narrow Void.Inorganic chemistry · 2023Article
- Electric Fields in Catalysis: From Enzymes to Molecular Catalysts.ACS catalysis · 2021Article
- Use of Crown Ether Functions as Secondary Coordination Spheres for the Manipulation of Ligand-Metal Intramolecular Electron Transfer in Copper-Guanidine Complexes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Harnessing the active site triad: merging hemilability, proton responsivity, and ligand-based redox-activity.Dalton transactions (Cambridge, England : 2003) · 2020Article
- Synthetic methodology for preparation of dinitrosyl iron complexes.Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry · 2019Review
- Selective deoxygenation of nitrate to nitrosyl using trivalent chromium and the Mashima reagent: reductive silylation.Chemical science · 2019Article
- Hemilabile Proton Relays and Redox Activity Lead to {FeNO}Journal of the American Chemical Society · 2018Article
Corrections and comments
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Authors and funding
6 authors.
Funding
Abstract
Metal complexes composed of redox-active pyridinediimine (PDI) ligands are capable of forming ligand-centered radicals. In this Forum article, we demonstrate that integration of these types of redox-active sites with bioinspired secondary coordination sphere motifs produce direduced complexes, where the reduction potential of the ligand-based redox sites is uncoupled from the secondary coordination sphere. The utility of such ligand design was explored by encapsulating redox-inactive Lewis acidic cations via installation of a pendant benzo-15-crown-5 in the secondary coordination sphere of a series of Fe(PDI) complexes. Fe(
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