Evidence map›Paper›PMID 29596367›Full record

ReviewMolecules (Basel, Switzerland)2018

Carbene Transfer Reactions Catalysed by Dyes of the Metalloporphyrin Group.

Mário M Q Simões, Daniel T G Gonzaga, Mariana F C Cardoso, Luana da S M Forezi, Ana T P C Gomes, Fernando de C da Silva, Vítor F Ferreira, Maria G P M S Neves, José A S Cavaleiro

Open access · goldAbstract readReview
In one paragraph

Review in Molecules (Basel, Switzerland), 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.

0numbers the graph read from it
0cells of the map it votes in
7citing papers in PubMed
1.8field-weighted citation impact, top 16% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

7 citing papers in PubMed, 28 citations in OpenAlex.

  1. Iron-Catalyzed Cyclopropanation of Allenes Using Unactivated Alkyl Sulfonium Salts.Angewandte Chemie (International ed. in English) · 2026
    Article
  2. Review
  3. Article
  4. Article
  5. Article
  6. Article
  7. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors at 2 institutions in 2 countries.

Mário M Q SimõesDepartment of Chemistry & Organic Chemistry, Natural Products and Food Stuffs Unit (QOPNA), University of Aveiro, 3810-193 Aveiro, Portugal. msimoes@ua.pt.ORCID 0000-0001-9071-2252
Daniel T G GonzagaDepartamento de Química Orgânica, Universidade Federal Fluminense, Niterói 24020-150, RJ, Brazil. danieltadeugonzaga@yahoo.com.br.
Mariana F C CardosoDepartamento de Química Orgânica, Universidade Federal Fluminense, Niterói 24020-150, RJ, Brazil. marianafcc83@hotmail.com.
Luana da S M ForeziDepartamento de Química Orgânica, Universidade Federal Fluminense, Niterói 24020-150, RJ, Brazil. ana.peixoto@ua.pt.
Ana T P C GomesDepartment of Chemistry & Organic Chemistry, Natural Products and Food Stuffs Unit (QOPNA), University of Aveiro, 3810-193 Aveiro, Portugal. gneves@ua.pt.ORCID 0000-0002-7953-8166
Fernando de C da SilvaDepartamento de Química Orgânica, Universidade Federal Fluminense, Niterói 24020-150, RJ, Brazil. gqofernando@vm.uff.br.ORCID 0000-0002-2042-3778
Vítor F FerreiraDepartamento de Tecnologia Farmacêutica Química, Universidade Federal Fluminense, Niterói 24241-002, RJ, Brazil. vitorferreira@id.uff.br.
Maria G P M S NevesDepartment of Chemistry & Organic Chemistry, Natural Products and Food Stuffs Unit (QOPNA), University of Aveiro, 3810-193 Aveiro, Portugal.ORCID 0000-0002-7953-8166
José A S CavaleiroDepartment of Chemistry & Organic Chemistry, Natural Products and Food Stuffs Unit (QOPNA), University of Aveiro, 3810-193 Aveiro, Portugal. jcavaleiro@ua.pt.ORCID 0000-0001-5495-5126
Universidade Federal Fluminense · BRUniversity of Aveiro · PT

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Carbene transfer reactions are very important transformations in organic synthesis, allowing the generation of structurally challenging products by catalysed cyclopropanation, cyclopropenation, carbene C-H, N-H, O-H, S-H, and Si-H insertion, and olefination of carbonyl compounds. In particular, chiral and achiral metalloporphyrins have been successfully explored as biomimetic catalysts for these carbene transfer reactions under both homogeneous and heterogeneous conditions. In this work the use of synthetic metalloporphyrins (MPorph, M = Fe, Ru, Os, Co, Rh, Ir, Sn) as homogeneous or heterogeneous catalysts for carbene transfer reactions in the last years is reviewed, almost exclusively focused on the literature since the year 2010, except when reference to older publications was deemed to be crucial.

Indexed as

MetalloporphyrinsMethanecarbeneMetalloporphyrinsMethanecarbenescyclopropanationcyclopropenationmetalloporphyrinsolefinationporphyrinsX-H insertion

Identifiers

PMID29596367
PMCPMC6017490
OpenAlexW2795190763

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.