ArticleAnalytical chemistry2018
Direct Electrochemical Sensing of Hydrogen Sulfide without Sulfur Poisoning.
Article in Analytical chemistry, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
17 citing papers in PubMed, 102 citations in OpenAlex.
- Reactive Sulfur Species and Protein Persulfidation: An Emerging Redox Axis in Human Health and Disease.Current issues in molecular biology · 2025Review
- Selectivity optimization of real-time and continuous sensing of endogenous HMikrochimica acta · 2025Article
- A Bioluminescent Probe for HACS bio & med chem Au · 2025Article
- Pb-based metal organic framework as substrate: Chemical vapor generation-visual/smartphone colorimetric analytical system for sensitive and selective detection of sulfide ion in water and beers.Food chemistry: X · 2024Article
- Difunctional Fluorescent Probes for Iron and Hydrogen Sulfide Detection Based on Diphenyl Derivative.Journal of fluorescence · 2024Article
- A Chalcone-based Fluorescence Probe for HJournal of fluorescence · 2024Article
- Novel HRSC advances · 2023Article
- Review of Chemical Sensors for Hydrogen Sulfide Detection in Organisms and Living Cells.Sensors (Basel, Switzerland) · 2023Review
- Planar carbon electrodes for real-time quantification of hydrogen sulfide release from cells.Sensors & diagnostics · 2023Article
- The Roadmap of Graphene-Based Sensors: Electrochemical Methods for Bioanalytical Applications.Biosensors · 2022Review
- Biocompatible Electrochemical Sensor Based on Platinum-Nickel Alloy Nanoparticles for In Situ Monitoring of Hydrogen Sulfide in Breast Cancer Cells.Nanomaterials (Basel, Switzerland) · 2022Article
- Trace Hydrogen Sulfide Sensing Inspired by Polyoxometalate-Mediated Aerobic Oxidation.ACS central science · 2021Article
- Characterization of Endogenous and Extruded HACS chemical biology · 2021Article
- Rapid measurement of hydrogen sulphide in human blood plasma using a microfluidic method.Scientific reports · 2019Article
- Design, Validation, and Application of an Enzyme-Coupled Hydrogen Sulfide Detection Assay.Biochemistry · 2019Article
- A direct and selective electrochemical hydrogen sulfide sensor.Analytica chimica acta · 2019Article
- A novel near-infrared fluorescent probe for highly selective recognition of hydrogen sulfide and imaging in living cells.RSC advances · 2018Article
Corrections and comments
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Authors and funding
2 authors at 1 institution in 1 country.
Funding
Abstract
An electrochemical method capable of direct, real-time detection of hydrogen sulfide was developed using triple pulse amperometry (TPA) to mitigate sulfur poisoning and its related passivation of the working electrode surface. Through repeated cycles of discrete potential pulses, the electrooxidation of surface-adsorbed elemental sulfur to water-soluble sulfate ions was exploited to regenerate the glassy carbon electrode surface and maintain consistent sensor performance. Amperometric measurements and X-ray photoelectron spectroscopy surface analysis demonstrated that the TPA sensors provided enhanced analytical performance via decreased sulfur accumulation relative to low-potential (≤+0.7 V) constant potential amperometry. Sensors operated under optimized TPA parameters retained high sensitivity (57.4 ± 13.0 nA/μM), a wide linear dynamic range (150 nM-15 μM), fast response times (<10 s), and a submicromolar detection limit (<100 nM) upon consecutive calibration cycles. The sensitivity and response time achieved were comparable to or better than current electrochemical sensors. Moreover, the simplicity of the method eliminates the need for external redox mediators or semipermeable membranes.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.