Evidence map›Paper›PMID 29559652›Full record

ArticleNature communications2018

Understanding and tailoring ligand interactions in the self-assembly of branched colloidal nanocrystals into planar superlattices.

Andrea Castelli, Joost de Graaf, Sergio Marras, Rosaria Brescia, Luca Goldoni, Liberato Manna, Milena P Arciniegas

Abstract read
In one paragraph

Article in Nature communications, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

  1. Article
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Andrea CastelliIstituto Italiano di Tecnologia, Via Morego 30, 16163, Genova, Italy.
Joost de GraafSUPA, School of Physics and Astronomy, The University of Edinburgh, King's Buildings, Peter Guthrie Tait Road, Edinburgh, EH9 3FD, UK. j.degraaf@ed.ac.uk.
Sergio MarrasIstituto Italiano di Tecnologia, Via Morego 30, 16163, Genova, Italy.
Rosaria BresciaIstituto Italiano di Tecnologia, Via Morego 30, 16163, Genova, Italy.
Luca GoldoniIstituto Italiano di Tecnologia, Via Morego 30, 16163, Genova, Italy.
Liberato MannaIstituto Italiano di Tecnologia, Via Morego 30, 16163, Genova, Italy.
Milena P ArciniegasIstituto Italiano di Tecnologia, Via Morego 30, 16163, Genova, Italy. milena.arciniegas@iit.it.

Funding

European Research Council 240111
6 · The paper itself

Abstract

Colloidal nanocrystals can self-assemble into highly ordered superlattices. Recent studies have focused on changing their morphology by tuning the nanocrystal interactions via ligand-based surface modification for simple particle shapes. Here we demonstrate that this principle is transferable to and even enriched in the case of a class of branched nanocrystals made of a CdSe core and eight CdS pods, so-called octapods. Through careful experimental analysis, we show that the octapods have a heterogeneous ligand distribution, resembling a cone wrapping the individual pods. This induces location-specific interactions that, combined with variation of the pod aspect ratio and ligands, lead to a wide range of planar superlattices assembled at an air-liquid interface. We capture these findings using a simple simulation model, which reveals the necessity of including ligand-based interactions to achieve these superlattices. Our work evidences the sensitivity that ligands offer for the self-assembly of branched nanocrystals, thus opening new routes for metamaterial creation.

Identifiers

PMID29559652
PMCPMC5861251

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.