ArticleAngewandte Chemie (International ed. in English)2018
Catalysis with Pnictogen, Chalcogen, and Halogen Bonds.
Article in Angewandte Chemie (International ed. in English), 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 91 papers.
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91 citing papers in PubMed.
- Short Sb···Sb Contacts in Polymorphic Tris(p-Tolyl)Antimony: A Hallmark of Organoantimony(III) Solid-State Chemistry?Angewandte Chemie (International ed. in English) · 2026Article
- σ-Hole Engineering Enables Selective Supramolecular Isomer Formation in Sb(III) Hosts.Inorganic chemistry · 2026Article
- Chalcogen-bonding-mediated chiral recognition and enantioenrichment of organoselenocyanates.Chemical science · 2026Article
- Neutral chiral bidentate tellurium-triazoles for enantioselective non-covalent chalcogen-bonding catalysis.Nature communications · 2026Article
- Pnictogen-bonding-crosslinked polymer networks: constructing self-healing materials.Chemical science · 2026Article
- A Substrate-Dependent Redox Catalysis of Tellurenyl Species Involving Oxidation States +I, +II, and +IV.Inorganic chemistry · 2026Article
- Design Rules for Sb and Bi Porphyrin Capsules: Para-Substitution Effects and Pnictogen Bond Conformational Control.Inorganic chemistry · 2026Article
- Harnessing Pnictogen and Chalcogen Bonding for Cross-Electrophile C-POrganic letters · 2026Article
- Probing the Hybrid σ/π-Holes in spChemphyschem : a European journal of chemical physics and physical chemistry · 2025Article
- Pnictogen-Bonding Catalysis: Copolymerization of COACS catalysis · 2025Article
- Matere bond identification in non-crystalline materials by using X-ray photoelectron spectroscopy.Chemical science · 2025Article
- Medical and Nonmedical Applications of Synthetic Transmembrane Anion Transporters.Chemical reviews · 2025Review
- Chalcogen-Guided Control of Azoarene Photoswitching: Tuning Excited-State Energies Through Electronic Property Modulation.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Modulation of Lanthanide Luminescence with the Mechanical Bond: Antenna-Emitter Confinement in a Compact [2]Rotaxane.Angewandte Chemie (International ed. in English) · 2025Article
- Taxonomy of Chemical Bondings: Opportunities and Challenges.Angewandte Chemie (International ed. in English) · 2025Article
- Metal-Involving Bifurcated Halogen Bonding with Iodide and Platinum(II) Center.International journal of molecular sciences · 2025Article
- Pnictogen bonding enabled photosynthesis of chiral selenium-containing pyridines from pyridylphosphonium salts.Fundamental research · 2025Article
- Amphoteric chalcogen-bonding and halogen-bonding rotaxanes for anion or cation recognition.Nature chemistry · 2025Article
- Illuminating the Performance of Electron Withdrawing Groups in Halogen Bonding.Chemphyschem : a European journal of chemical physics and physical chemistry · 2024Article
- Anion Recognition-Directed Supramolecular Catalysis with Functional Macrocycles and Molecular Cages.Accounts of chemical research · 2024Article
31 more citing papers are in PubMed but not listed here.
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4 authors.
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Abstract
Halogen- and chalcogen-based σ-hole interactions have recently received increased interest in non-covalent organocatalysis. However, the closely related pnictogen bonds have been neglected. In this study, we introduce conceptually simple, neutral, and monodentate pnictogen-bonding catalysts. Solution and in silico binding studies, together with high catalytic activity in chloride abstraction reactions, yield compelling evidence for operational pnictogen bonds. The depth of the σ holes is easily varied with different substituents. Comparison with homologous halogen- and chalcogen-bonding catalysts shows an increase in activity from main group VII to V and from row 3 to 5 in the periodic table. Pnictogen bonds from antimony thus emerged as by far the best among the elements covered, a finding that provides most intriguing perspectives for future applications in catalysis and beyond.
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