ArticleNature communications2018
Elucidating anionic oxygen activity in lithium-rich layered oxides.
Article in Nature communications, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 38 papers.
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Who cites it
38 citing papers in PubMed, 342 citations in OpenAlex.
- Constructing Li-O-Vacancy Configuration Coupling with a Layered/Spinel Mixed Structure in Li-Deficient Li-Rich Layered Oxides to Realize Stable Oxygen Redox.Materials (Basel, Switzerland) · 2026Article
- Recovery of High-Voltage Oxygen Redox Activity by Eliminating Residual Oxygen Dimers.Journal of the American Chemical Society · 2025Article
- An amorphous Li-V-O-F cathode with tetrahedral coordination and O-O formal redox at low voltage.Nature materials · 2025Article
- Transition Metal Slab Gliding: One Key Process for Activating Anionic Redox Reaction in P2-Type Transition Metal Oxide Cathodes.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Metal-to-metal charge transfer for stabilizing high-voltage redox in lithium-rich layered oxide cathodes.Science advances · 2025Article
- Revealing the Role of Ruthenium on the Performance of P2-Type NaSmall (Weinheim an der Bergstrasse, Germany) · 2024Article
- Strong Magnetic Exchange Interactions and Delocalized Mn-O States Enable High-Voltage Capacity in the Na-Ion Cathode P2-NaChemistry of materials : a publication of the American Chemical Society · 2024Article
- Material Engineering Solutions toward Selective Redox Catalysts for Chemical-Looping-Based Olefin Production Schemes: A Review.Energy & fuels : an American Chemical Society journal · 2024Review
- New information about the cyclable capacity fading process of a pouch cell with Li-rich layered oxide cathodes.RSC advances · 2024Article
- Highly reversible transition metal migration in superstructure-free Li-rich oxide boosting voltage stability and redox symmetry.Nature communications · 2024Article
- Fluorination Effect on Lithium- and Manganese-Rich Layered Oxide Cathodes.ACS energy letters · 2024Article
- High-energy all-solid-state lithium batteries enabled by Co-free LiNiONature nanotechnology · 2024Article
- Scrutinizing formally NiChemical science · 2023Article
- Oxygen-deficient TiORSC advances · 2023Article
- The Importance of Structural Uniformity and Chemical Homogeneity in Cobalt-Free Lithium Excess Nickel Manganese Oxide Cathodes.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2023Article
- Fabricating Heterostructures for Boosting the Structure Stability of Li-Rich Cathodes.ACS omega · 2023Article
- Reduced Potential Barrier of Sodium-Substituted Disordered Rocksalt Cathode for Oxygen Evolution Electrocatalysts.Nanomaterials (Basel, Switzerland) · 2022Article
- Eliminating interfacial O-involving degradation in Li-rich Mn-based cathodes for all-solid-state lithium batteries.Science advances · 2022Article
- Surface reduction in lithium- and manganese-rich layered cathodes for lithium ion batteries drives voltage decay.Journal of materials chemistry. A · 2022Article
- A medium-entropy transition metal oxide cathode for high-capacity lithium metal batteries.Nature communications · 2022Article
Corrections and comments
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Authors and funding
14 authors at 5 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Recent research has explored combining conventional transition-metal redox with anionic lattice oxygen redox as a new and exciting direction to search for high-capacity lithium-ion cathodes. Here, we probe the poorly understood electrochemical activity of anionic oxygen from a material perspective by elucidating the effect of the transition metal on oxygen redox activity. We study two lithium-rich layered oxides, specifically lithium nickel metal oxides where metal is either manganese or ruthenium, which possess a similar structure and discharge characteristics, but exhibit distinctly different charge profiles. By combining X-ray spectroscopy with operando differential electrochemical mass spectrometry, we reveal completely different oxygen redox activity in each material, likely resulting from the different interaction between the lattice oxygen and transition metals. This work provides additional insights into the complex mechanism of oxygen redox and development of advanced high-capacity lithium-ion cathodes.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.