ArticleOrganic letters2018
Regiocontrolled Wacker Oxidation of Cinnamyl Azides.
Article in Organic letters, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
What it found
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Who cites it
11 citing papers in PubMed.
- Wacker Oxidation of Trisubstituted Alkenes: Pd(II)-Catalyzed Oxidative Ring Expansion of Exocyclic α,β-Unsaturated Carbonyl to 2-Fluoro-1,3-Dicarbonyl Compounds.Angewandte Chemie (International ed. in English) · 2025Article
- Synthesis and In Silico Analysis of New Polyheterocyclic Molecules Derived from [1,4]-Benzoxazin-3-one and Their Inhibitory Effect against Pancreatic α-Amylase and Intestinal α-Glucosidase.Molecules (Basel, Switzerland) · 2024Article
- Palladium/Iron-Catalyzed Wacker-Type Oxidation of Aliphatic Terminal and Internal Alkenes Using OACS omega · 2023Article
- Wacker Oxidation of Methylenecyclobutanes: Scope and Selectivity in an Unusual Setting.Angewandte Chemie (International ed. in English) · 2023Article
- A Cascade Reaction of Cinnamyl Azides with Acrylates Directly Generates Tetrahydro-Pyrrolo-Pyrazole Heterocycles.The Journal of organic chemistry · 2020Article
- Selective Wacker type oxidation of a macrocyclic diene to the corresponding monounsaturated ketone used as fragrance.RSC advances · 2019Article
- Allylic azides: synthesis, reactivity, and the Winstein rearrangement.Organic & biomolecular chemistry · 2019Review
- Dative Directing Group Effects in Ti-Catalyzed [2+2+1] Pyrrole Synthesis: Chemo- and Regioselective Alkyne Heterocoupling.ACS catalysis · 2019Article
- Total Synthesis of Asperphenins A and B.Organic letters · 2018Article
- Evidence for a Sigmatropic and an Ionic Pathway in the Winstein Rearrangement.The Journal of organic chemistry · 2018Article
- On the Winstein rearrangement: equilibrium and mechanism.ARKIVOC : free online journal of organic chemistryArticle
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
A highly regioselective Wacker oxidation has been developed for the oxidation of cinnamyl azides. The catalytic oxidation tolerates the azide functionality, and more than 15 β-azido ketones were isolated (25-92% yield). High regioselectivity for the aryl ketone is observed in all cases. A robustness screen was conducted to determine functional group tolerance. The products of the oxidaiton can be readily diversified.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.