Evidence map›Paper›PMID 29491787›Full record

ArticleDesigned monomers and polymers2017

Concentration effects in the base-catalyzed hydrolysis of oligo(ethylene glycol)- and amine-containing methacrylic monomers.

Oleg A Kazantsev, Dmitry V Orekhov, Alexey P Sivokhin, Denis M Kamorin, Maria V Savinova

Open access · goldAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Designed monomers and polymers, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
0.8field-weighted citation impact, top 20% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed, 18 citations in OpenAlex.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors at 1 institution in 1 country.

Oleg A KazantsevDepartment of Chemical Engineering, Nizhny Novgorod State Technical University n.a. R.E. Alekseev, Nizhny Novgorod, Russia.
Dmitry V OrekhovDepartment of Chemical Engineering, Nizhny Novgorod State Technical University n.a. R.E. Alekseev, Nizhny Novgorod, Russia.
Alexey P SivokhinDepartment of Chemical Engineering, Nizhny Novgorod State Technical University n.a. R.E. Alekseev, Nizhny Novgorod, Russia.ORCID 0000-0002-6387-6574
Denis M KamorinDepartment of Chemical Engineering, Nizhny Novgorod State Technical University n.a. R.E. Alekseev, Nizhny Novgorod, Russia.
Maria V SavinovaDepartment of Chemical Engineering, Nizhny Novgorod State Technical University n.a. R.E. Alekseev, Nizhny Novgorod, Russia.
Nizhny Novgorod State Technical University · RU

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Concentration effects in the base-catalyzed hydrolysis of water-soluble methacrylates (3-(N,N-dimethylaminoethyl) methacrylate (DMAEMA), 2-hydroxyethyl methacrylate (HEMA) and oligo(ethylene glycol) methacrylates (OEGMAs)) have been studied. These monomers are rapidly hydrolyzed in the presence of bases at the room temperature in dilute aqueous solutions, but the reaction rate decreases sharply in highly concentrated solutions. A clear correlation was found between a form of the viscosity isotherm for DMAEMA solutions and the concentration dependence of the autocatalytic hydrolysis rate which indicates the connection of process kinetics with the structure of solutions. These data should be considered when carrying out homo- and copolymerization of the previously mentioned monomers in aqueous solutions.

Indexed as

2-hydroxyethyl methacrylate3-(N,N-dimethylaminoethyl) methacrylatebase-catalyzed hydrolysiskineticsOligo(ethylene glycol) methacrylatesstructure of a solution

Identifiers

PMID29491787
PMCPMC5812183
OpenAlexW2530042295

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.