Evidence map›Paper›PMID 29483850›Full record

ArticleAdvanced synthesis & catalysis2017

Gold-catalyzed Fluorination of Alkynyl Esters and Ketones: Efficient Access to Fluorinated 1,3-Dicarbonyl Compounds.

Xiaojun Zeng, Zhichao Lu, Shiwen Liu, Gerald B Hammond, Bo Xu

Abstract read
In one paragraph

Article in Advanced synthesis & catalysis, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.

0numbers the graph read from it
0cells of the map it votes in
8citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

8 citing papers in PubMed.

  1. Article
  2. Review
  3. Article
  4. Article
  5. Fluorohydration of alkynes via I(I)/I(III) catalysis.Beilstein journal of organic chemistry · 2020
    Article
  6. Article
  7. Article
  8. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Xiaojun ZengCollege of Chemistry, Chemical Engineering and Biotechnology, Donghua University, 2999 North Renmin Lu, Shanghai 201620, China.
Zhichao LuDepartment of Chemistry, University of Louisville, Louisville, KY 40292, USA.
Shiwen LiuCollege of Chemistry, Chemical Engineering and Biotechnology, Donghua University, 2999 North Renmin Lu, Shanghai 201620, China.
Gerald B HammondDepartment of Chemistry, University of Louisville, Louisville, KY 40292, USA.
Bo XuCollege of Chemistry, Chemical Engineering and Biotechnology, Donghua University, 2999 North Renmin Lu, Shanghai 201620, China.

Funding

Nucleophilic Halogenation ReagentsR01GM121660 · NIGMS · UNIVERSITY OF LOUISVILLE · PI HAMMOND, GERALD B · 2017 to 2021
$1.5M
NIGMS NIH HHS R01 GM121660
6 · The paper itself

Abstract

We developed an efficient synthesis of 2-fluoro-1,3-dicarbonyl compounds using readily available alkynyl ketones or esters as starting material. The key step is the insertion of hydrogen fluoride (HF) to the gold carbene intermediate generated from cationic gold catalyzed addition of

Indexed as

1,3-Dicarbonyl CompoundsAlkynyl Esters and KetonesFluorinationGold Catalysis

Identifiers

PMID29483850
PMCPMC5824727

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.