ArticleNature chemistry2018
Transferring the entatic-state principle to copper photochemistry.
Article in Nature chemistry, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
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Who cites it
16 citing papers in PubMed, 70 citations in OpenAlex.
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- Protein-Enforced Ligand Environments Reshape Classical Coordination Preferences in Copper Polypyridyl Complexes.Journal of the American Chemical Society · 2026Article
- Crystal Lattice-Induced Stress modulates Photoinduced Jahn-Teller Distortion Dynamics.ACS physical chemistry Au · 2024Article
- Chemical Regulation of Fluorescence Lifetime.Chemical & biomedical imaging · 2023Review
- X-ray spectroscopy station for sample characterization at ELI Beamlines.Scientific reports · 2023Article
- Manipulating electron transfer - the influence of substituents on novel copper guanidine quinolinyl complexes.Chemical science · 2022Article
- First experiments with a water-jet plasma X-ray source driven by the novel high-power-high-repetition rate L1 Allegra laser at ELI Beamlines.Journal of synchrotron radiation · 2021Article
- Electrically Induced Mixed Valence Increases the Conductivity of Copper Helical Metallopolymers.Advanced materials (Deerfield Beach, Fla.) · 2021Article
- X-ray-Based Techniques to Study the Nano-Bio Interface.ACS nano · 2021Article
- Flexibility of the CueR Metal Site Probed by Instantaneous Change of Element and Oxidation State from AgChemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Taking a snapshot of the triplet excited state of an OLED organometallic luminophore using X-rays.Nature communications · 2020Article
- Optimizing Group Transfer Catalysis by Copper Complex with Redox-Active Ligand in an Entatic State.iScience · 2020Article
- Copper(I) Phosphinooxazoline Complexes: Impact of the Ligand Substitution and Steric Demand on the Electrochemical and Photophysical Properties.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Rotaxane PtChemical science · 2020Article
- Heteroleptic Coordination Environments in Metal-Mediated DNA G-Quadruplexes.Frontiers in chemistry · 2020Article
- Low Reorganization Energy for Electron Self-Exchange by a Formally Copper(III,II) Redox Couple.Inorganic chemistry · 2019Article
Corrections and comments
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Authors and funding
24 authors at 5 institutions in 4 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The entatic state denotes a distorted coordination geometry of a complex from its typical arrangement that generates an improvement to its function. The entatic-state principle has been observed to apply to copper electron-transfer proteins and it results in a lowering of the reorganization energy of the electron-transfer process. It is thus crucial for a multitude of biochemical processes, but its importance to photoactive complexes is unexplored. Here we study a copper complex-with a specifically designed constraining ligand geometry-that exhibits metal-to-ligand charge-transfer state lifetimes that are very short. The guanidine-quinoline ligand used here acts on the bis(chelated) copper(I) centre, allowing only small structural changes after photoexcitation that result in very fast structural dynamics. The data were collected using a multimethod approach that featured time-resolved ultraviolet-visible, infrared and X-ray absorption and optical emission spectroscopy. Through supporting density functional calculations, we deliver a detailed picture of the structural dynamics in the picosecond-to-nanosecond time range.
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.