ArticleAngewandte Chemie (International ed. in English)2018
The Dewar Isomer of 1,2-Dihydro-1,2-azaborinines: Isolation, Fragmentation, and Energy Storage.
Article in Angewandte Chemie (International ed. in English), 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 34 papers.
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Who cites it
34 citing papers in PubMed.
- Modular and Stereoselective Synthesis of Cyclobutane β-Amino Alcohols.Angewandte Chemie (International ed. in English) · 2026Article
- Molecular solar thermal energy storage in nitrone-oxaziridine pairs with widely tunable thermal half-lives.Chemical science · 2026Article
- Substituent Tightrope: Balancing Energy Storage and Stability of Dihydroazaborinine Molecular Solar Thermal Energy Storage Candidates.The Journal of organic chemistry · 2026Article
- Time-resolved Coulomb explosion imaging of a photochemical ring opening reaction.Nature communications · 2026Article
- Fatigue-Resistant Dithienylarene Photoswitches with Acid-Regulated Thermal Ring Opening.ACS omega · 2026Article
- Thermally Bistable Stiff Stilbene Photoswitches and Polymer Applications.Chemical record (New York, N.Y.) · 2026Article
- Time-Resolved Laser-Induced Ring-Opening and Dissociation Dynamics in Bromothiophene Isomers.Journal of the American Chemical Society · 2026Article
- Ethynylene-Linked 1,2-Dihydro-1,2-Azaborinines With High Energy Densities for Efficient Molecular Solar Thermal Energy Storage.ChemSusChem · 2026Article
- Switching Shapes: Reversible Three Species Photoisomerization of Substituted 1,2-Dihydro-1,2-azaborinines.Journal of the American Chemical Society · 2026Article
- A Catalyst-Controlled Divergent Rearomatization of BN-Benzvalene.Journal of the American Chemical Society · 2026Article
- Positional Isomerization of 1,2-Azaborine through BN-Benzvalene.Journal of the American Chemical Society · 2026Article
- Mallory-Type Reactivity of 1,2-Dihydroazaborinines: 6π-Electrocyclization-[1,5]-H Shift Cascade toward BN-Doped Polycyclic Frameworks.Organic letters · 2026Article
- Mechanistic Insight into the Thermal Ring Opening of the Dewar Isomer of 1,2-Dihydro-1,2-azaborinines.JACS Au · 2025Article
- Norbornadiene Quadricyclane as Multimode Photoswitches: Synergistic Light and Protonation-Controlled Heat Release.ChemSusChem · 2025Article
- Tuning Electrocatalytic Energy Release in Norbornadiene Based Molecular Solar Thermal Systems Through Substituent Effects.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- An Azobenzene-Based Liquid Molecular Solar Thermal (MOST) Storage System-Energy Carrier and Solvent.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Article
- A Nitrilium-TypeJournal of the American Chemical Society · 2025Article
- Synthesis of Chiral δ-Aminoboronic Esters by Enantioselective Hydrogenation of 1,2-Azaborines.Angewandte Chemie (International ed. in English) · 2025Article
- Ring-Opening Metathesis Polymerization of 1,2-Dihydroazete Derivatives.Angewandte Chemie (International ed. in English) · 2025Article
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Abstract
The photochemistry of 1,2-dihydro-1,2-azaborinine derivatives was studied under matrix isolation conditions and in solution. Photoisomerization occurs exclusively to the Dewar valence isomers upon irradiation with UV light (>280 nm) with high quantum yield (46 %). Further photolysis with UV light (254 nm) results in the formation of cyclobutadiene and an iminoborane derivative. The thermal electrocyclic ring-opening reaction of the Dewar valence isomer back to the 1,2-dihydro-1-tert-butyldimethylsilyl-2-mesityl-1,2-azaborinine has an activation barrier of (27.0±1.2) kcal mol
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