ArticleAngewandte Chemie (International ed. in English)2018
Confinement Effects on the Benzene Orientational Structure.
Article in Angewandte Chemie (International ed. in English), 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
4 citing papers in PubMed.
- Probing the Behaviour of Fluids Confined in Porous Materials by Neutron Scattering: Applications to COChemPlusChem · 2024Review
- Neutron Scattering Studies of Heterogeneous Catalysis.Chemical reviews · 2023Review
- Hyperloop-like diffusion of long-chain molecules under confinement.Nature communications · 2023Article
- Confinement Effects on the Benzene Orientational Structure.Angewandte Chemie (International ed. in English) · 2018Article
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Authors and funding
5 authors.
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Abstract
Liquids under confinement exhibit different properties compared with their corresponding bulk phases, for example, miscibility, phase transitions, and diffusion. The underlying cause is the local ordering of molecules, which is usually only studied using pure simulation methods. Herein, we derive experimentally the structure of benzene confined in MCM-41 using total neutron scattering measurements. The study reveals a layering of molecules across a pore, and four concentric cylindrical shells can be distinguished for a pore with the radius of 18 Å. The nanoscale confinement of the liquid has a major effect on the spatial and orientational correlations observed between the molecules, when compared with the structure of the bulk liquid. These differences are most marked for molecules in parallel configurations, and this suggests differences in chemical reactivity between the confined and bulk liquids.
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