Evidence map›Paper›PMID 29445234›Full record

ArticleScientific reports2018

Tuning the Optical Properties of Silicon Quantum Dots via Surface Functionalization with Conjugated Aromatic Fluorophores.

Mohammed Abdelhameed, Diego Rota Martir, Shalimar Chen, William Z Xu, Olabode O Oyeneye, Subrata Chakrabarti, Eli Zysman-Colman, Paul A Charpentier

Open access · goldAbstract read
In one paragraph

Article in Scientific reports, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers, 1 of them a synthesis that pooled it.

0numbers the graph read from it
0cells of the map it votes in
12citing papers in PubMed, 1 pooled it
2.3field-weighted citation impact, top 11% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

12 citing papers in PubMed, 1 synthesis or guideline pooled it, 42 citations in OpenAlex.

  1. Quantum Dots in Ocular Surface: A Systematic Review.Wiley interdisciplinary reviews. Nanomedicine and nanobiotechnology
    Pooled it
  2. Silicon Flavylium Polymethine Dyes for Shortwave Infrared Imaging.Journal of the American Chemical Society · 2026
    Article
  3. Article
  4. Article
  5. Review
  6. Article
  7. Article
  8. Article
  9. Article
  10. Eco-Friendly Colloidal Quantum Dot-Based Luminescent Solar Concentrators.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2019
    Review
  11. Quantum dot therapeutics: a new class of radical therapies.Journal of biological engineering · 2019
    Review
  12. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors at 2 institutions in 2 countries.

Mohammed AbdelhameedDepartment of Chemical and Biochemical Engineering, Western University, London, Ontario, N6A 5B9, Canada.
Diego Rota MartirOrganic Semiconductor Centre, EaStCHEM School of Chemistry, University of St Andrews, St Andrews, Fife, KY16 9ST, UK.
Shalimar ChenDepartment of Pathology and Laboratory Medicine, Schulich School of Medicine and Dentistry, Western University, London, N6A 5B9, Ontario, Canada.
William Z XuDepartment of Chemical and Biochemical Engineering, Western University, London, Ontario, N6A 5B9, Canada.
Olabode O OyeneyeDepartment of Chemical and Biochemical Engineering, Western University, London, Ontario, N6A 5B9, Canada.
Subrata ChakrabartiDepartment of Pathology and Laboratory Medicine, Schulich School of Medicine and Dentistry, Western University, London, N6A 5B9, Ontario, Canada.
Eli Zysman-ColmanOrganic Semiconductor Centre, EaStCHEM School of Chemistry, University of St Andrews, St Andrews, Fife, KY16 9ST, UK. eli.zysman-colman@st-andrews.ac.uk.ORCID 0000-0001-7183-6022
Paul A CharpentierDepartment of Chemical and Biochemical Engineering, Western University, London, Ontario, N6A 5B9, Canada. pcharpentier@eng.uwo.ca.
Western University · CAUniversity of St Andrews · GB

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Silicon Quantum Dots (SQDs) have recently attracted great interest due to their excellent optical properties, low cytotoxicity, and ease of surface modification. The size of SQDs and type of ligand on their surface has a great influence on their optical properties which is still poorly understood. Here we report the synthesis and spectroscopic studies of three families of unreported SQDs functionalized by covalently linking to the aromatic fluorophores, 9-vinylphenanthrene, 1-vinylpyrene, and 3-vinylperylene. The results showed that the prepared functionalized SQDs had a highly-controlled diameter by HR-TEM, ranging from 1.7-2.1 nm. The photophysical measurements of the assemblies provided clear evidence for efficient energy transfer from the fluorophore to the SQD core. Fӧrster energy transfer is the likely mechanism in these assemblies. As a result of the photogenerated energy transfer process, the emission color of the SQD core could be efficiently tuned and its emission quantum efficiency enhanced. To demonstrate the potential application of the synthesized SQDs for bioimaging of cancer cells, the water-soluble perylene- and pyrene-capped SQDs were examined for fluorescent imaging of HeLa cells. The SQDs were shown to be of low cytotoxicity.

Identifiers

PMID29445234
PMCPMC5813013
OpenAlexW2785335878

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.