ArticleJournal of the American Chemical Society2018
Unified Total Synthesis of Pyrroloazocine Indole Alkaloids Sheds Light on Their Biosynthetic Relationship.
Article in Journal of the American Chemical Society, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed, 78 citations in OpenAlex.
- Total Synthesis of (+)-Raistrickindole A.Organic letters · 2026Article
- Asymmetric Synthesis of the Pentacyclic Framework ofOrganic letters · 2025Article
- Combining the best of both worlds: radical-based divergent total synthesis.Beilstein journal of organic chemistry · 2023Review
- Iron-Catalyzed Cycloisomerization and C-C Bond Activation to Access Non-canonical Tricyclic Cyclobutanes.Angewandte Chemie (International ed. in English) · 2022Article
- Synthesis of Natural Products by C-H Functionalization of Heterocycless.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Review
- The 100 facets of the Passerini reaction.Chemical science · 2021Review
- Access to Indole-Annulated Medium-Sized Lactams through Protonation/Deuteration-Induced Ring-Opening of Spiroindolines.ACS omega · 2021Article
- Asymmetric construction of pyrido[1,2-Chemical science · 2020Article
- Excimer and Exciplex Formation in Gold(I) Complexes Preconditioned by Aurophilic Interactions.Angewandte Chemie (International ed. in English) · 2020Review
- Radicals in natural product synthesis.Chemical Society reviews · 2018Article
- Development of the Vinylogous Pictet-Spengler Cyclization and Total Synthesis of (±)-Lundurine A.Angewandte Chemie (International ed. in English) · 2018Article
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Authors and funding
4 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The total synthesis of seven members of the lapidilectine and grandilodine family of alkaloids has been accomplished in racemic and enantiopure form without protection/deprotection of functional groups. The two key steps, an 8- endo-dig hydroarylation and a 6- exo-trig photoredox cyclization, were catalyzed using gold. A rationale for the formation of the cyclopropane ring of the lundurines is also provided.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.