ArticleAngewandte Chemie (International ed. in English)2018
Encapsulation of Crabtree's Catalyst in Sulfonated MIL-101(Cr): Enhancement of Stability and Selectivity between Competing Reaction Pathways by the MOF Chemical Microenvironment.
Article in Angewandte Chemie (International ed. in English), 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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12 citing papers in PubMed.
- Spatial Orientation-Dependent Double Hydrogen Bond/Photoredox Cooperative Catalysis in Metal-Organic Frameworks.Angewandte Chemie (International ed. in English) · 2026Article
- Mapping proton and carbon dioxide electrocatalytic reductions at a Rh complex byChemical science · 2026Article
- Supramolecular Chemistry in Metal-Organic Framework Materials.Advanced materials (Deerfield Beach, Fla.) · 2025Review
- Article
- Ultrasound-assisted continuous aqueous synthesis of sulfonate, imidazolate, and carboxylate MOFs with high space time yield.Communications chemistry · 2025Article
- Host-Guest Synergy of Metal-Organic Frameworks for Enhanced Near-Infrared Ultrafast Laser Responsiveness.ACS central science · 2025Article
- Diffusion-programmed catalysis in nanoporous material.Nature communications · 2025Article
- Metal-organic framework boosts heterogeneous electron donor-acceptor catalysis.Nature communications · 2023Article
- Isolating reactive metal-based species in Metal-Organic Frameworks - viable strategies and opportunities.Chemical science · 2020Review
- Reversible Encapsulation of Xenon and CHAngewandte Chemie (International ed. in English) · 2019Article
- Increasing Alkyl Chain Length in a Series of Layered Metal-Organic Frameworks Aids Ultrasonic Exfoliation to Form Nanosheets.Inorganic chemistry · 2019Article
- Encapsulation of Crabtree's Catalyst in Sulfonated MIL-101(Cr): Enhancement of Stability and Selectivity between Competing Reaction Pathways by the MOF Chemical Microenvironment.Angewandte Chemie (International ed. in English) · 2018Article
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9 authors.
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Abstract
Crabtree's catalyst was encapsulated inside the pores of the sulfonated MIL-101(Cr) metal-organic framework (MOF) by cation exchange. This hybrid catalyst is active for the heterogeneous hydrogenation of non-functionalized alkenes either in solution or in the gas phase. Moreover, encapsulation inside a well-defined hydrophilic microenvironment enhances catalyst stability and selectivity to hydrogenation over isomerization for substrates bearing ligating functionalities. Accordingly, the encapsulated catalyst significantly outperforms its homogeneous counterpart in the hydrogenation of olefinic alcohols in terms of overall conversion and selectivity, with the chemical microenvironment of the MOF host favouring one out of two competing reaction pathways.
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