ReviewMolecules (Basel, Switzerland)2018
Dinuclear Nickel(I) and Palladium(I) Complexes for Highly Active Transformations of Organic Compounds.
Review in Molecules (Basel, Switzerland), 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed, 57 citations in OpenAlex.
- Dynamics of Metal-Metal Bond Dissociation in Pd-Pd and Ni-Ni Complexes: Reorganization and Redistribution Reactions of the Metalloradicals.Angewandte Chemie (International ed. in English) · 2025Article
- Palladium-Catalyzed Carbonylative Difunctionalization of Unactivated Alkenes Initiated by Unstabilized Enolates.Angewandte Chemie (International ed. in English) · 2023Article
- Emerging Trends in Cross-Coupling: Twelve-Electron-Based LChemical reviews · 2022Review
- Potassium Trimethylsilanolate-Promoted, Anhydrous Suzuki-Miyaura Cross-Coupling Reaction Proceeds via the "Boronate Mechanism": Evidence for the Alternative Fork in the Trail.Journal of the American Chemical Society · 2022Article
- Changes in ligand coordination mode induce bimetallic C-C coupling pathways.Dalton transactions (Cambridge, England : 2003) · 2022Article
- Catalysis with Palladium(I) Dimers.Angewandte Chemie (International ed. in English) · 2021Review
- Ligand Protonation Triggers HAngewandte Chemie (International ed. in English) · 2021Article
- A Next-Generation Air-Stable Palladium(I) Dimer Enables Olefin Migration and Selective C-C Coupling in Air.Angewandte Chemie (International ed. in English) · 2020Article
- Editorial for "Organometallic Chemistry" Section, in JournalMolecules (Basel, Switzerland) · 2020Article
- Mechanistic details of the cobalt-mediated dehydrogenative dimerization of aminoquinoline-directed benzamides.Chemical science · 2020Article
- Fluorine-Substituted Arylphosphine for an NHC-Ni(I) System, Air-Stable in a Solid State but Catalytically Active in Solution.Molecules (Basel, Switzerland) · 2019Article
- Computational Approach to Molecular Catalysis by 3d Transition Metals: Challenges and Opportunities.Chemical reviews · 2019Article
Corrections and comments
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Authors and funding
3 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
In typical catalytic organic transformations, transition metals in catalytically active complexes are present in their most stable valence states, such as palladium(0) and (II). However, some dimeric monovalent metal complexes can be stabilized by auxiliary ligands to form diamagnetic compounds with metal-metal bonding interactions. These diamagnetic compounds can act as catalysts while retaining their dimeric forms, split homolytically or heterolytically into monomeric forms, which usually have high activity, or in contrast, become completely deactivated as catalysts. Recently, many studies using group 10 metal complexes containing nickel and palladium have demonstrated that under specific conditions, the active forms of these catalyst precursors are not mononuclear zerovalent complexes, but instead dinuclear monovalent metal complexes. In this mini-review, we have surveyed the preparation, reactivity, and the catalytic processes of dinuclear nickel(I) and palladium(I) complexes, focusing on mechanistic insights into the precatalyst activation systems and the structure and behavior of nickel and palladium intermediates.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.