ArticleAngewandte Chemie (International ed. in English)2018
Visible-Light-Mediated Decarboxylative Radical Additions to Vinyl Boronic Esters: Rapid Access to γ-Amino Boronic Esters.
Article in Angewandte Chemie (International ed. in English), 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 37 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
37 citing papers in PubMed, 143 citations in OpenAlex.
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- (Poly)Borylated Species as Modern Reactive Groups toward Unusual Synthetic Applications.Angewandte Chemie (International ed. in English) · 2026Review
- Palladium-Catalyzed Gem-Diborylalkylation of Silyl Enol Ethers and N-Vinylacetamide via Diboryl Carbon-Centered Radicals.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Thermally activated delayed fluorescence materials: innovative design and advanced application in biomedicine, catalysis and electronics.RSC advances · 2025Review
- Photogeneration of α-Bimetalloid Radicals via Selective Activation of Multifunctional C1 Units.Journal of the American Chemical Society · 2024Article
- Photoinduced Triphenylphosphine and Iodide Salt Promoted Reductive Decarboxylative Coupling.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Generation and Application of Homoallylic α,α-Diboryl Radicals via Diboron-Promoted Ring-Opening of Vinyl Cyclopropanes: cis-Diastereoselective Borylative Cycloaddition.Chemistry (Weinheim an der Bergstrasse, Germany) · 2024Article
- Direct decarboxylative Giese amidations: photocatalyticChemical science · 2023Article
- Photocatalyzed regioselective hydrosilylation for the divergent synthesis of geminal and vicinal borosilanes.Nature communications · 2023Article
- Cu-catalyzed enantioselective decarboxylative cyanationChemical science · 2023Article
- Photoredox-Mediated Deoxygenative Radical Additions of Aromatic Acids to Vinyl Boronic Esters and gem-Diborylalkenes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- The Impact of Boron Hybridisation on Photocatalytic Processes.Angewandte Chemie (International ed. in English) · 2022Review
- Photoinduced metal-free borylation of aryl halides catalysed by anChemical science · 2022Article
- A Modular Approach to the Antifungal Sphingofungin Family: Concise Total Synthesis of Sphingofungin A and C.Angewandte Chemie (International ed. in English) · 2022Article
- Photoredox-mediated hydroalkylation and hydroarylation of functionalized olefins for DNA-encoded library synthesis.Chemical science · 2021Article
- Photoactive electron donor-acceptor complex platform for Ni-mediated C(spChemical science · 2021Article
- Rhodium-catalysed selective C-C bond activation and borylation of cyclopropanes.Chemical science · 2021Article
- Photoredox-enabled 1,2-dialkylation of α-substituted acrylatesChemical science · 2021Article
- General Access toACS catalysis · 2020Article
Corrections and comments
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Authors and funding
5 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The synthesis of alkyl boronic esters by direct decarboxylative radical addition of carboxylic acids to vinyl boronic esters is described. The reaction proceeds under mild photoredox catalysis and involves an unprecedented single-electron reduction of an α-boryl radical intermediate to the corresponding anion. The reaction is amenable to a diverse range of substrates, including α-amino, α-oxy, and alkyl carboxylic acids, thus providing a novel method to rapidly access boron-containing molecules of potential biological importance.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.