ArticleJournal of environmental quality2017
Aging of Dissolved Copper and Copper-based Nanoparticles in Five Different Soils: Short-term Kinetics vs. Long-term Fate.
Article in Journal of environmental quality, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed.
- Review
- Stabilization of Cu Species in UiO-66 Metal-Organic Framework for COSmall (Weinheim an der Bergstrasse, Germany) · 2026Article
- Virucidal Efficacy of Laser-Generated Copper Nanoparticle Coatings against Model Coronavirus and Herpesvirus.ACS applied materials & interfaces · 2025Article
- Copper-Modified Titania-Based Photocatalysts for the Efficient Hydrogen Production under UV and Visible Light from Aqueous Solutions of Glycerol.Nanomaterials (Basel, Switzerland) · 2022Article
- Dissolution kinetics and solubility of copper oxide nanoparticles as affected by soil properties and aging time.Environmental science and pollution research international · 2022Article
- Transformation and release of micronized Cu used as a wood preservative in treated wood in wetland soil.Environmental pollution (Barking, Essex : 1987) · 2021Article
- Comparison of foliar spray and soil irrigation of biogenic CuO nanoparticles (NPs) on elemental uptake and accumulation in lettuce.Environmental science and pollution research international · 2021Article
- Transformation of copper oxide and copper oxide nanoparticles in the soil and their accumulation by Hordeum sativum.Environmental geochemistry and health · 2021Article
- Root System Architecture, Copper Uptake and Tissue Distribution in Soybean (Plants (Basel, Switzerland) · 2020Article
- The Effects of In Vivo Exposure to Copper Oxide Nanoparticles on the Gut Microbiome, Host Immunity, and Susceptibility to a Bacterial Infection in Earthworms.Nanomaterials (Basel, Switzerland) · 2020Article
- Retention of nano PbO in saturated columns and its dissolution kinetics in soils.Environmental science and pollution research international · 2020Article
Corrections and comments
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Authors and funding
8 authors.
Funding
Abstract
With the growing availability and use of copper-based nanomaterials (Cu-NMs), there is increasing concern regarding their release and potential impact on the environment. In this study, the short-term (≤5 d) aging profile and the long-term (135 d) speciation of dissolved Cu, copper oxide, and copper sulfide nanoparticles (CuO-NPs and CuS-NPs) were investigated in five different soils using X-ray absorption spectroscopy. Soil pH was found to strongly influence the short-term chemistry of the Cu-NMs added at 100 mg kg above background. Low pH soils promoted rapid dissolution of CuO-NPs that effectively aligned their behavior to that of dissolved Cu within 3 d. In higher pH soils, CuO-NPs persisted longer due to slower dissolution in the soil and resulted in contrasting short-term speciation compared with dissolved Cu, which formed copper hydroxides and carbonates that were reflective of the soil chemistry. Organic matter appeared to slow the dissolution process, but in the long term, the speciation of Cu added as dissolved Cu, CuO-NPs, and CuS-NPs were found to be same for each soil. The results imply that, in the short term, Cu-NMs may exhibit unique behavior in alkaline soils compared with their conventional forms (e.g., in the event of an adverse leaching event), but in the long term (≥135 d), their fates are dictated by the soil properties, are independent of the initial Cu form, and are likely to present minimal risk of nanospecific Cu-NM impact in the soil environment for the concentration studied here.
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