ArticleOrganic letters2018
Palladium-Catalyzed C-H Bond Acetoxylation via Electrochemical Oxidation.
Article in Organic letters, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 24 papers.
What it found
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Who cites it
24 citing papers in PubMed.
- Aminoborate-Catalyzed Reductive Counterreactions for Oxidative Electrosynthetic Transformations.The Journal of organic chemistry · 2024Article
- Electrifying Hydroformylation Catalysts Exposes Voltage-Driven C-C Bond Formation.Journal of the American Chemical Society · 2024Article
- An Unusual Rearrangement of Pyrazole Nitrene and Coarctate Ring-Opening/Recyclization Cascade: Formal CH-Acetoxylation and Azide/Amine Conversion without External Oxidants and Reductants.Molecules (Basel, Switzerland) · 2023Article
- Metal-free electrochemical dihydroxylation of unactivated alkenes.Nature communications · 2023Article
- Electrochemical Late-Stage Functionalization.Chemical reviews · 2023Review
- Electrochemical Palladium-Catalyzed Oxidative Carbonylation-Cyclization of Enallenols.Angewandte Chemie (International ed. in English) · 2022Article
- Cu(II) carboxylate arene C─H functionalization: Tuning for nonradical pathways.Science advances · 2022Article
- Facile and general electrochemical deuteration of unactivated alkyl halides.Nature communications · 2022Article
- Advances on the Merger of Electrochemistry and Transition Metal Catalysis for Organic Synthesis.Chemical reviews · 2022Review
- Cross-dehydrogenative N-N couplings.Chemical science · 2021Review
- Electrocatalysis as an enabling technology for organic synthesis.Chemical Society reviews · 2021Article
- Rhoda-Electrocatalyzed Bimetallic C-H Oxygenation by Weak O-Coordination.Angewandte Chemie (International ed. in English) · 2021Article
- Mediator-Enabled Electrocatalysis with Ligandless Copper for Anaerobic Chan-Lam Coupling Reactions.Journal of the American Chemical Society · 2021Article
- Organic Electrochemistry: Molecular Syntheses with Potential.ACS central science · 2021Review
- Divergent rhodium-catalyzed electrochemical vinylic C-H annulation of acrylamides with alkynes.Nature communications · 2021Article
- New Redox Strategies in Organic Synthesis by Means of Electrochemistry and Photochemistry.ACS central science · 2020Review
- Evolution of High-Valent Nickela-Electrocatalyzed C-H Activation: From Cross(-Electrophile)-Couplings to Electrooxidative C-H Transformations.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Review
- Enantioselective Pallada-Electrocatalyzed C-H Activation by Transient Directing Groups: Expedient Access to Helicenes.Angewandte Chemie (International ed. in English) · 2020Article
- Azaruthena(II)-bicyclo[3.2.0]heptadiene: Key Intermediate for Ruthenaelectro(II/III/I)-catalyzed Alkyne Annulations.Angewandte Chemie (International ed. in English) · 2020Article
- Carboxylate breaks the arene C-H bondChemical science · 2020Article
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Authors and funding
4 authors.
Funding
Abstract
Here we describe the development of a method for the Pd-catalyzed electrochemical acetoxylation of C-H bonds. The oxidation step of the catalytic cycle is probed through cyclic voltammetry and bulk electrolysis studies of a preformed palladacycle of 8-methylquinoline. A catalytic system for C-H acetoxylation is then developed and optimized with respect to the cell configuration, rate of oxidation, and chemistry at the counter electrode. This transformation is then applied to substrates containing various directing groups and to the acetoxylation of both C(sp
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Registered trials
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