ArticleJournal of the American Chemical Society2018
Nickel-Catalyzed Stereoselective Arylboration of Unactivated Alkenes.
Article in Journal of the American Chemical Society, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 34 papers.
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Who cites it
34 citing papers in PubMed.
- Nickel-catalyzed radical relay enabled chemoselective fluoroalkyl-borylation of [1.1.1]propellane under kinetic control.Science advances · 2026Article
- Head-tail carboboration of multisubstituted alkenes enabled by chain recognition.Nature chemistry · 2025Article
- Diverse Synthesis of C-Glycosides by Stereoselective Ni-Catalyzed Carboboration of Glycals.Journal of the American Chemical Society · 2024Article
- Ni-Catalyzed 1,1- and 1,3-Aminoboration of Unactivated Alkenes.Journal of the American Chemical Society · 2023Article
- Copper-catalyzed defluorinative arylboration of vinylarenes with polyfluoroarenes.Chemical science · 2023Article
- Arylboration of Enecarbamates for the Synthesis of Borylated Saturated N-Heterocycles.Angewandte Chemie (International ed. in English) · 2022Article
- Regioselective catalytic carbonylation and borylation of alkynes with aryldiazonium salts toward α-unsubstituted β-boryl ketones.Chemical science · 2022Article
- Directed, nickel-catalyzed 1,2-alkylsulfenylation of alkenyl carbonyl compounds.Chemical science · 2022Article
- Cooperative Pd/Cu Catalysis for Alkene Arylboration: Opportunities for Divergent Reactivity.ACS catalysis · 2022Article
- Catalytic Arylboration of Spirocyclic Cyclobutenes: Rapid Access to Highly Substituted Spiro[3.n]alkanes.ACS catalysis · 2021Article
- Nickel-Catalyzed Dearomative Arylboration of Indoles: Regioselective Synthesis of C2- and C3-Borylated Indolines.Journal of the American Chemical Society · 2021Article
- Nickel-catalyzed enantioselective 1,2-vinylboration of styrenes.Chemical science · 2021Article
- Catalyst-free carbosilylation of alkenes using silyl boronates and organic fluorides via selective C-F bond activation.Nature communications · 2021Article
- Enantioselective Allylation of Alkenyl Boronates Promotes a 1,2-Metalate Rearrangement with 1,3-Diastereocontrol.Journal of the American Chemical Society · 2021Article
- Construction of congested CspChemical science · 2021Article
- Three-Component Ni-Catalyzed Silylacylation of Alkenes.ACS catalysis · 2021Article
- Mechanism-Based Design of an Amide-Directed Ni-Catalyzed Arylboration of Cyclopentene Derivatives.Organic letters · 2021Article
- Rhodium-catalysed selective C-C bond activation and borylation of cyclopropanes.Chemical science · 2021Article
- Transition-Metal-Catalyzed 1,2-Carboboration of Alkenes: Strategies, Mechanisms, and Stereocontrol.Israel journal of chemistry · 2020Article
- A unified approach for divergent synthesis of contiguous stereodiads employing a small boronyl group.Nature communications · 2020Article
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
A Ni-catalyzed method for arylboration is disclosed. The method allows for highly stereoselective arylboration of unactivated alkenes. The reactions utilize a simple Ni-catalyst and work with a broad range of alkenes and aryl bromides. The products represent useful intermediates for chemical synthesis due to the versatility of the C-B bond. Preliminary mechanistic details of the method are also disclosed.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.