ArticleNature chemistry2018
Late-stage chemoselective functional-group manipulation of bioactive natural products with super-electrophilic silylium ions.
Article in Nature chemistry, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
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Who cites it
15 citing papers in PubMed, 55 citations in OpenAlex.
- Catalytic Hydrosilylation Deoxygenation: Synthesizing Polysiloxanes While Upcycling Polymers to Alkanes.Angewandte Chemie (International ed. in English) · 2026Article
- Leveraging the Proximity Effect: Direct Ester to Ether Deoxygenation Using Fiddler-Crab-Type Borane Catalysts.Angewandte Chemie (International ed. in English) · 2026Article
- Anomer-Selective Vorbrüggen Reaction for the Catalytic Synthesis of CJournal of the American Chemical Society · 2026Article
- Selective Reductions of Esters to Aldehydes: Extended Scope and Downstream Reactivity.The Journal of organic chemistry · 2025Article
- Direct nucleophilic and electrophilic activation of alcohols using a unified boron-based organocatalyst scaffold.Nature communications · 2023Article
- Chemoselective Homologation-Deoxygenation Strategy Enabling the Direct Conversion of Carbonyls into (Organic letters · 2020Article
- Defunctionalisation catalysed by boron Lewis acids.Chemical science · 2020Review
- Reductive Deamination with Hydrosilanes Catalyzed by B(CAngewandte Chemie (International ed. in English) · 2020Article
- B(CACS catalysis · 2020Article
- B(CAdvanced synthesis & catalysis · 2020Article
- Article
- An Experimental Acidity Scale for Intramolecularly Stabilized Silyl Lewis Acids.Chemistry (Weinheim an der Bergstrasse, Germany) · 2019Article
- Site Selective Amide Reduction of Cyclosporine A Enables Diverse Derivation of an Important Cyclic Peptide.Organic letters · 2019Article
- Tris(pentafluorophenyl)borane-Catalyzed Reactions Using Silanes.Molecules (Basel, Switzerland) · 2019Review
- Silylated cyclopentadienes as competent silicon Lewis acid catalysts.Chemical science · 2018Article
Corrections and comments
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Authors and funding
3 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The selective (and controllable) modification of complex molecules with disparate functional groups (for example, natural products) is a long-standing challenge that has been addressed using catalysts tuned to perform singular transformations (for example, C-H hydroxylation). A method whereby reactions with diverse functional groups within a single natural product are feasible depending on which catalyst or reagent is chosen would widen the possible structures one could obtain. Fluoroarylborane catalysts can heterolytically split Si-H bonds to yield an oxophilic silylium (R
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.