Evidence map›Paper›PMID 29254886›Full record

ArticleJournal of hazardous materials2019

Chlorpyrifos degradation via photoreactive TiO

Jeffrey Farner Budarz, Ellen M Cooper, Courtney Gardner, Emina Hodzic, P Lee Ferguson, Claudia K Gunsch, Mark R Wiesner

Open access · greenAbstract read
In one paragraph

Article in Journal of hazardous materials, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.

0numbers the graph read from it
0cells of the map it votes in
10citing papers in PubMed
2.3field-weighted citation impact, top 11% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

10 citing papers in PubMed, 86 citations in OpenAlex.

  1. Fenton and Photo-Fenton Degradation of Chlorpyrifos Using α-MnInternational journal of molecular sciences · 2026
    Article
  2. Recent Advances in TiOInternational journal of molecular sciences · 2026
    Review
  3. Article
  4. Article
  5. Review
  6. Article
  7. Article
  8. Article
  9. Synthesis and photocatalytic activity of porous ZnO stabilized by TiOEnvironmental science and pollution research international · 2021
    Article
  10. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors at 1 institution in 1 country.

Jeffrey Farner BudarzDepartment of Civil and Environmental Engineering, Pratt School of Engineering, Duke University, Durham, NC, 27708, USA.
Ellen M CooperDuke University Nicholas School of the Environment, Durham, NC 27708, USA.
Courtney GardnerDepartment of Civil and Environmental Engineering, Pratt School of Engineering, Duke University, Durham, NC, 27708, USA.
Emina HodzicDuke University Nicholas School of the Environment, Durham, NC 27708, USA.
P Lee FergusonDepartment of Civil and Environmental Engineering, Pratt School of Engineering, Duke University, Durham, NC, 27708, USA.
Claudia K GunschDepartment of Civil and Environmental Engineering, Pratt School of Engineering, Duke University, Durham, NC, 27708, USA.
Mark R WiesnerDepartment of Civil and Environmental Engineering, Pratt School of Engineering, Duke University, Durham, NC, 27708, USA. Electronic address: wiesner@duke.edu.
Duke University · US

Funding

Zebrafish as a Detector of Organophosphate ExposureP42ES010356 · NIEHS · DUKE UNIVERSITY · PI EDWARD D LEVIN · 2000 to 2026
$56.2M
Data commons for 'omic, microscopy and analysis core facilitiesS10OD018164 · OD · DUKE UNIVERSITY · PI WRAY, GREGORY A. · 2014 to 2014
$598k
NIEHS NIH HHS P42 ES010356NIH HHS S10 OD018164
6 · The paper itself

Abstract

High concentrations of pesticides enter surface waters following agricultural application, raising environmental and human health concerns. The use of photoreactive nanoparticles has shown promise for contaminant degradation and surface water remediation. However, it remains uncertain how the complexity of natural waters will impact the photodegradation process. Here, we investigate the photoreactivity of titanium dioxide nanoparticles, the capability to degrade the pesticide chlorpyrifos, and the effect of and impact on bacteria during the photodegradation process. Loss of chlorpyrifos in solution resulted solely from photocatalytic oxidation, with 80% degradation observed after 24 h in our reactor, either in the presence or absence of bacteria. Degradation of chlorpyrifos to chlorpyrifos oxon and 3,5,6-trichloro-2-pyridinol was observed via LC/MS-MS and effectively modeled for the given reactor conditions. Bacterial inactivation occurred over 60 min and was not impacted by the presence of chlorpyrifos. The relative affinity of bacteria and chlorpyrifos for the nanoparticle surface decreased the amount of Reactive Oxygen Species (ROS) detected in the bulk by up to 94%, suggesting that ROS measurements in simplified systems may overestimate the reactivity of photoreactive nanoparticles in complex environments.

Indexed as

Bacterial inactivationChlorpyrifosNanoparticlesPhotoreactivityTitanium dioxide

Identifiers

PMID29254886
PMCPMC5995634
OpenAlexW2772887345

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.