ArticleNature communications2017
Iron-based nanocatalyst for the acceptorless dehydrogenation reactions.
Article in Nature communications, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed, 116 citations in OpenAlex.
- Defective indium oxide as plasmonic catalyst for efficient photo-driven methanol steam reforming.Nature communications · 2026Article
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- Recent Advances in Carbon-Based Iron Catalysts for Organic Synthesis.Nanomaterials (Basel, Switzerland) · 2022Review
- Sustainable production of hydrogen with high purity from methanol and water at low temperatures.Nature communications · 2022Article
- Continuous Room-Temperature Hydrogen Release from Liquid Organic Carriers in a Photocatalytic Packed-Bed Flow Reactor.ChemSusChem · 2022Article
- Metal-free carbocatalyst for room temperature acceptorless dehydrogenation of N-heterocycles.Science advances · 2022Article
- A Perspective on Heterogeneous Catalysts for the Selective Oxidation of Alcohols.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Review
- Iron(II)-Catalyzed Aerobic Biomimetic Oxidation of N-Heterocycles.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Selective Acceptorless Dehydrogenation of Primary Amines to Imines by Core-Shell Cobalt Nanoparticles.Angewandte Chemie (International ed. in English) · 2020Article
- Iodine-catalyzed convergent aerobic dehydro-aromatization toward benzazoles and benzazines.RSC advances · 2020Article
- Copper-Promoted Functionalization of Organic Molecules: from Biologically Relevant Cu/OChemical reviews · 2019Review
- Iridium-based hydride transfer catalysts: from hydrogen storage to fine chemicals.Chemical communications (Cambridge, England) · 2018Article
Corrections and comments
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Authors and funding
4 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Development of sustainable catalytic systems for fundamentally important synthetic transformations and energy storage applications is an intellectually stimulating challenge. Catalytic dehydrogenation of feedstock chemicals, such as alcohols and amines to value-added products with the concomitant generation of dihydrogen is of much interest in the context of hydrogen economy and is an effective alternative to the classical oxidation reactions. Despite a number of homogeneous catalysts being identified for the acceptorless dehydrogenation, the use of high price and limited availability of precious metals and poor recovery of the catalyst have spurred interest in catalysis with more earth-abundant alternatives, especially iron. However, no report has described a reusable iron-based heterogeneous catalyst for oxidant-free and acceptorless dehydrogenation reactions. Here we replace expensive noble metal catalysts with an inexpensive, benign, and sustainable nanoscale iron catalyst for the efficient acceptorless dehydrogenation of N-heterocycles and alcohols with liberation of hydrogen gas.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.