ArticleProceedings of the National Academy of Sciences of the United States of America2017
Ultrafast rotation in an amphidynamic crystalline metal organic framework.
Article in Proceedings of the National Academy of Sciences of the United States of America, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 29 papers.
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Who cites it
29 citing papers in PubMed.
- Construction of molecular fans in metal-organic framework to overcome diffusion resistance for trace benzene capture.Nature communications · 2026Article
- Turn-on luminescence from molecular rotor realignment in metal-organic framework thin films.Nature communications · 2026Article
- Engineering molecular rotor-stator ligand architectures on copper nanoclusters for efficient photothermal conversion.Nature communications · 2026Article
- Engineering of Rotational Dynamics via Polymorph Manipulation.The journal of physical chemistry. A · 2024Article
- Long-Range and Coupled Rotor Dynamics in NOThe journal of physical chemistry. C, Nanomaterials and interfaces · 2024Article
- 2D hexagonal assembly of a dipolar rotor with a close interval of 0.8 nm using a triptycene-based supramolecular scaffold.Chemical science · 2024Article
- Unravelling Guest Dynamics in Crystalline Molecular Organics UsingJournal of the American Chemical Society · 2024Article
- Transition Metal Chelation Effect in MOF-253 Materials: Guest Molecule Adsorption Dynamics and Proposed Formic Acid Synthesis Investigated by Atomistic Simulations.Molecules (Basel, Switzerland) · 2024Article
- Understanding Cu(i) local environments in MOFsChemical science · 2024Article
- Quantum-accurate machine learning potentials for metal-organic frameworks using temperature driven active learning.npj computational materials · 2024Article
- Benzothiadiazole-based rotation and possible antipolar order in carboxylate-based metal-organic frameworks.Communications chemistry · 2023Article
- Controlling dynamics in extended molecular frameworks.Nature reviews. Chemistry · 2022Review
- Cascade Dynamics of Multiple Molecular Rotors in a MOF: Benchmark Mobility at a Few Kelvins and Dynamics Control by COJournal of the American Chemical Society · 2021Article
- Emergence of Coupled Rotor Dynamics in Metal-Organic Frameworks via Tuned Steric Interactions.Journal of the American Chemical Society · 2021Article
- Dipolar order in an amphidynamic crystalline metal-organic framework through reorienting linkers.Nature chemistry · 2021Article
- Photoresponsive porous materials.Nanoscale advances · 2021Review
- Quantum spin-liquid states in an organic magnetic layer and molecular rotor hybrid.Proceedings of the National Academy of Sciences of the United States of America · 2020Article
- Design of Metal-Organic Framework Templated Materials Using High-Throughput Computational Screening.Molecules (Basel, Switzerland) · 2020Article
- Correlated motion and mechanical gearing in amphidynamic crystalline molecular machines.Chemical science · 2020Review
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Amphidynamic crystals are an emergent class of condensed phase matter designed with a combination of lattice-forming elements linked to components that display engineered dynamics in the solid state. Here, we address the design of a crystalline array of molecular rotors with inertial diffusional rotation at the nanoscale, characterized by the absence of steric or electronic barriers. We solved this challenge with 1,4-bicyclo[2.2.2]octane dicarboxylic acid (BODCA)-MOF, a metal-organic framework (MOF) built with a high-symmetry bicyclo[2.2.2]octane dicarboxylate linker in a Zn
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.