ArticleScience advances2017
Stitching h-BN by atomic layer deposition of LiF as a stable interface for lithium metal anode.
Article in Science advances, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 25 papers.
What it found
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
25 citing papers in PubMed.
- Bi-Functional Extension on Heterogeneous ORR/OER Catalysis with 2D Materials for Li-ONano-micro letters · 2026Review
- Cesium Lead Chloride as an Artificial Solid Electrolyte Interphase for Enhanced Anode Protection in Lithium Metal Batteries.Chemistry of materials : a publication of the American Chemical Society · 2025Article
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- A Review of Carbon Nanofiber Materials for Dendrite-Free Lithium-Metal Anodes.Molecules (Basel, Switzerland) · 2024Review
- Influence of nano-BN inclusion and mechanism involved on aluminium-copper alloy.Scientific reports · 2024Article
- High Voltage Cycling Stability of LiF-Coated NMC811 Electrode.ACS applied materials & interfaces · 2024Article
- From Liquid to Solid-State Lithium Metal Batteries: Fundamental Issues and Recent Developments.Nano-micro letters · 2023Review
- Liquid electrolyte chemistries for solid electrolyte interphase construction on silicon and lithium-metal anodes.Chemical science · 2023Review
- Recent Advances in the Preparation and Application of Two-Dimensional Nanomaterials.Materials (Basel, Switzerland) · 2023Review
- Surface engineering toward stable lithium metal anodes.Science advances · 2023Review
- Tuning 4f-Center Electron Structure by Schottky Defects for Catalyzing Li Diffusion to Achieve Long-Term Dendrite-Free Lithium Metal Battery.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2022Article
- Epitaxial Growth of Diamond-Shaped AuMaterials (Basel, Switzerland) · 2021Article
- Atomic and Molecular Layer Deposition of Alkali Metal Based Thin Films.ACS applied materials & interfaces · 2021Article
- The Functions and Applications of Fluorinated Interface Engineering in Li-Based Secondary Batteries.Small science · 2021Article
- Computational study of X-doped hexagonal boron nitride (h-BN): structural and electronic properties (X = P, S, O, F, Cl).Journal of molecular modeling · 2021Article
- An ultrastable lithium metal anode enabled by designed metal fluoride spansules.Science advances · 2020Article
- Two-Dimensional Materials in Large-Areas: Synthesis, Properties and Applications.Nano-micro letters · 2020Review
- The intrinsic behavior of lithium fluoride in solid electrolyte interphases on lithium.Proceedings of the National Academy of Sciences of the United States of America · 2020Article
- Towards high energy density lithium battery anodes: silicon and lithium.Chemical science · 2019Review
Corrections and comments
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Authors and funding
12 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Defects are important features in two-dimensional (2D) materials that have a strong influence on their chemical and physical properties. Through the enhanced chemical reactivity at defect sites (point defects, line defects, etc.), one can selectively functionalize 2D materials via chemical reactions and thereby tune their physical properties. We demonstrate the selective atomic layer deposition of LiF on defect sites of h-BN prepared by chemical vapor deposition. The LiF deposits primarily on the line and point defects of h-BN, thereby creating seams that hold the h-BN crystallites together. The chemically and mechanically stable hybrid LiF/h-BN film successfully suppresses lithium dendrite formation during both the initial electrochemical deposition onto a copper foil and the subsequent cycling. The protected lithium electrodes exhibit good cycling behavior with more than 300 cycles at relatively high coulombic efficiency (>95%) in an additive-free carbonate electrolyte.
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.