ArticleThe Journal of organic chemistry2018
Rapidly Activating Pd-Precatalyst for Suzuki-Miyaura and Buchwald-Hartwig Couplings of Aryl Esters.
Article in The Journal of organic chemistry, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 21 papers.
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Who cites it
21 citing papers in PubMed.
- Metal-N-Heterocyclic Carbene Complexes in Buchwald-Hartwig Amination Reactions.Chemical reviews · 2025Review
- Article
- [(NHC)Pd(OAc)The Journal of organic chemistry · 2024Article
- A sustainable metal and base-free direct amidation of esters using water as a green solvent.RSC advances · 2023Article
- Alkylboronic acids as alkylating agents: photoredox-catalyzed alkylation reactions assisted by KChemical science · 2022Article
- Unified synthesis of multiply arylated alkanes by catalytic deoxygenative transformation of diarylketones.Chemical science · 2022Article
- Pd-Catalyzed Cross-Couplings: On the Importance of the Catalyst Quantity Descriptors, mol % and ppm.Organic process research & development · 2022Review
- Synthesis of Triarylmethanes via Palladium-Catalyzed Suzuki-Miyaura Reactions of Diarylmethyl Esters.Organometallics · 2021Article
- 6-Halo-2-pyridone as an efficient organocatalyst for ester aminolysis.RSC advances · 2021Article
- Suzuki-Miyaura Cross-Coupling of Esters by Selective O-C(O) Cleavage Mediated by Air- and Moisture-Stable [Pd(NHC)(μ-Cl)Cl]Catalysis science & technology · 2021Article
- Differences in the Performance of Allyl Based Palladium Precatalysts for Suzuki-Miyaura Reactions.Advanced synthesis & catalysis · 2020Article
- Oxidative Addition of Water, Alcohols, and Amines in Palladium Catalysis.Angewandte Chemie (International ed. in English) · 2020Article
- Nickel-Catalyzed Synthesis of Dialkyl Ketones from the Coupling of N-Alkyl Pyridinium Salts with Activated Carboxylic Acids.Angewandte Chemie (International ed. in English) · 2020Article
- Palladium Complexes Based on Ylide-Functionalized Phosphines (YPhos): Broadly Applicable High-Performance Precatalysts for the Amination of Aryl Halides at Room Temperature.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Iron-Catalyzed C(spMolecules (Basel, Switzerland) · 2020Article
- Palladium-Catalyzed Suzuki-Miyaura Reactions of Aspartic Acid Derived Phenyl Esters.Organic letters · 2019Article
- Cross-Coupling and Related Reactions: Connecting Past Success to the Development of New Reactions for the Future.Organometallics · 2019Article
- Solvent- and transition metal-free amide synthesis from phenyl esters and aryl amines.RSC advances · 2019Article
- Well-Defined Pre-Catalysts in Amide and Ester Bond Activation.Molecules (Basel, Switzerland) · 2019Review
- Pd-Catalyzed Suzuki-Miyaura Cross-Coupling of Pentafluorophenyl Esters.Molecules (Basel, Switzerland) · 2018Article
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Authors and funding
5 authors.
Funding
Abstract
Esters are valuable electrophiles for cross-coupling due to their ubiquity and ease of synthesis. However, harsh conditions are traditionally required for the effective cross-coupling of ester substrates. Utilizing a recently discovered precatalyst, Pd-catalyzed Suzuki-Miyaura and Buchwald-Hartwig reactions involving cleavage of the C(acyl)-O bond of aryl esters that proceed under mild conditions are reported. The Pd(II) precatalyst is highly active because it is reduced to the Pd(0) active species more rapidly than previous precatalysts.
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