ArticleNature communications2017
Controlling thermal reactivity with different colors of light.
Article in Nature communications, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
12 citing papers in PubMed.
- Toward Chromoselective Transformations in Biological Systems: Perspectives and Challenges.Angewandte Chemie (International ed. in English) · 2026Review
- Diverse reactivity of maleimides in polymer science and beyond.Polymer international · 2025Article
- Main chain selective polymer degradation: controlled by the wavelength and assembly.Chemical science · 2024Article
- Synergistic interplay between photoisomerization and photoluminescence in a light-driven rotary molecular motor.Nature communications · 2022Article
- Force-reversible chemical reaction at ambient temperature for designing toughened dynamic covalent polymer networks.Nature communications · 2022Article
- Two Faces of the Bi-O Bond: PhotochemicallyEuropean journal of inorganic chemistry · 2022Article
- Photoinduced Processes as a Way to Sustainable Polymers and Innovation in Polymeric Materials.Polymers · 2021Review
- Photoclick Chemistry: A Bright Idea.Chemical reviews · 2021Review
- Light-fueled dynamic covalent crosslinking of single polymer chains in non-equilibrium states.Chemical science · 2020Article
- Green light triggered [2+2] cycloaddition of halochromic styrylquinoxaline-controlling photoreactivity by pH.Nature communications · 2020Article
- Development of tethered dual catalysts: synergy between photo- and transition metal catalysts for enhanced catalysis.Chemical science · 2020Article
- Multimaterial actinic spatial control 3D and 4D printing.Nature communications · 2019Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The ability to switch between thermally and photochemically activated reaction channels with an external stimulus constitutes a key frontier within the realm of chemical reaction control. Here, we demonstrate that the reactivity of triazolinediones, powerful coupling agents in biomedical and polymer research, can be effectively modulated by an external photonic field. Specifically, we show that their visible light-induced photopolymerization leads to a quantitative photodeactivation, thereby providing a well-defined off-switch of their thermal reactivity. Based on this photodeactivation, we pioneer a reaction manifold using light as a gate to switch between a UV-induced Diels-Alder reaction with photocaged dienes and a thermal addition reaction with alkenes. Critically, the modulation of the reactivity by light is reversible and the individually addressable reaction pathways can be repeatedly accessed. Our approach thus enables a step change in photochemically controlled reactivity, not only in small molecule ligations, yet importantly in controlled surface and photoresist design.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.