ArticleScientific reports2017
The sensitivity of donor - acceptor charge transfer to molecular geometry in DAN - NDI based supramolecular flower-like self-assemblies.
Article in Scientific reports, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed, 37 citations in OpenAlex.
- Electron donor-acceptor hybrid bonding polymers exhibit symmetry breaking and ferroelectricity.Journal of materials chemistry. C · 2026Article
- Marine-derived carbon dots: a safe and effective solution for noise-induced hearing loss.Journal of nanobiotechnology · 2026Article
- Peptide-Induced Ferroelectricity in Charge-Transfer Supramolecular Materials.Advanced materials (Deerfield Beach, Fla.) · 2026Article
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- Isoelectronic Push-Pull Fluorescent Difluoroborates: Halogen Bonding and Photophysical Properties.The Journal of organic chemistry · 2025Article
- Short Peptide-Based Smart Thixotropic Hydrogels.Gels (Basel, Switzerland) · 2022Review
- Charge Transfer Complexes of 1,3,6-Trinitro-9,10-phenanthrenequinone with Polycyclic Aromatic Compounds.Molecules (Basel, Switzerland) · 2021Article
- Photoactive organic material discovery with combinatorial supramolecular assembly.Nanoscale advances · 2019Review
Corrections and comments
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Authors and funding
10 authors at 4 institutions in 5 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
A charge-transfer (CT) complex self-assembled from an electron acceptor (NDI-EA: naphthalene diimide with appended diamine) and an electron donor (DAN: phosphonic acid-appended dialkoxynapthalene) in aqueous medium. The aromatic core of the NDI and the structure of DAN1 were designed to optimize the dispersive interactions (π-π and van der Waals interactions) in the DAN1-NDI-EA self-assembly, while the amino groups of NDI also interact with the phosphonic acid of DAN1 via electrostatic forces. This arrangement prevented crystallization and favored the directional growth of 3D flower nanostructures. This molecular geometry that is necessary for charge transfer to occur was further evidenced by using a mismatching DAN2 structure. The flower-shaped assembly was visualized by scanning electron and transmission electron microscopy. The formation of the CT complex was determined by UV-vis and cyclic voltammetry and the photoinduced electron transfer to produce the radical ion pair was examined by femtosecond laser transient absorption spectroscopic measurements.
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Registered trials
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