ArticleProceedings of the National Academy of Sciences of the United States of America2017
Chiral intertwined spirals and magnetic transition dipole moments dictated by cylinder helicity.
Article in Proceedings of the National Academy of Sciences of the United States of America, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 50 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
50 citing papers in PubMed.
- A Doubly Twisted Molecular Nanocarbon With Substantial π-Overlap: Facile Synthesis, Chiral Resolution, and Through-Space Electronic Coupling.Angewandte Chemie (International ed. in English) · 2026Article
- Highly Selective Construction of DSmall (Weinheim an der Bergstrasse, Germany) · 2026Article
- Amplified chiroptic response in a multi-helical penta-perylene structure.Chemical science · 2026Article
- Artificial Intelligence Predictions in Huge Chemical Spaces: Chiroptical Properties of [6]-helicene Family.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Trap-assisted circularly polarized organic photodetector.Nature communications · 2026Article
- Tuning Circular Dichroism and Circularly Polarised Luminescence in Single Crystals of a Perylene Diimide Macrocycle.Angewandte Chemie (International ed. in English) · 2026Article
- Improving the conjugation of organic ligands enhances the antenna effect and promotes the luminescence and optical imaging of chiral mononuclear Eu(iii) complexes.Chemical science · 2026Article
- Dynamic Covalent Platform for Chiroptically Tunable Figure-Eight Macrocycles from Preorganized Alkaloidal Scaffolds.JACS Au · 2026Article
- Quadruply Bridging Strategy Intensifies Circularly Polarized Luminescence of Azapyrenophanes.Journal of the American Chemical Society · 2026Article
- A Precisely Bromo-Functionalized [9]Cycloparaphenylene as a Platform for Late-Stage Multisite π-Extension Toward Chiral Nanohoops.Angewandte Chemie (International ed. in English) · 2026Article
- Synthesis of Enantiopure [3]Cyclorubicenes.Angewandte Chemie (International ed. in English) · 2026Article
- Strong Second Harmonic Generation and Nonlinear Optical Activity in Chiral Supramolecular Polymers.The journal of physical chemistry letters · 2025Article
- Quantum Chemistry Calculations of Circularly Polarized Luminescence (CPL): From Spectral Modeling to Molecular Design.Chemical reviews · 2025Review
- Expanded segments of three-dimensional carbonaceous nets with chirality: synthesis and structures.Chemical science · 2025Article
- Spring-Like Behavior in [8]Helicene Diimides: How Helical Pitch Governs Optical Anisotropy and Electronic Conjugation.Angewandte Chemie (International ed. in English) · 2025Article
- Design and performance optimization of circularly polarized luminescent materials based on lanthanide helicates.Scientific reports · 2025Article
- Acid/Base-Responsive Circularly Polarized Luminescence Emitters with Configurationally Stable Nitrogen Stereogenic Centers.Advanced materials (Deerfield Beach, Fla.) · 2025Article
- Introducing Prism[4]arene: A Macrocycle with Enantiomerically Resolvable Inherent Chirality and Intriguing Chiroptical Properties.Journal of the American Chemical Society · 2025Article
- Enantio- and Diastereoselective Synthesis and Spiral-Stair-Like Single Helix Assembly of Figure-Eight Cyclophenylenes.Angewandte Chemie (International ed. in English) · 2025Article
- Spherical Amides withMolecules (Basel, Switzerland) · 2025Article
Corrections and comments
- Erratum issued
Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The presence of anomalous chirality in a roll of graphitic carbon sheets has been recognized since the discovery of carbon nanotubes, which are becoming available in higher quantities through the isolation of chiral single-wall congeners with high purity. Exploration of the properties arising from cylinder chirality is expected to expand the scope of tubular entities in the future. By studying molecular fragments of helical carbon nanotubes, we herein reveal interesting properties that arise from this chirality. The chirality of nanoscale cylinders resulted in chirality of larger dimensions in the form of a double-helix assembly. Cylinder chirality in solution gave rise to a large dissymmetry factor of metal-free entities in circular polarized luminescence. Theoretical investigations revealed the pivotal role of cylindrical shapes in enhancing magnetic dipole transition moments to yield extreme rotatory strength. Unique effects of cylinder chirality in this study may prompt the development of tubular entities, for instance, toward chiroptical applications.
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