ArticleThe Journal of organic chemistry2017
Direct Synthesis of Secondary Benzylic Alcohols Enabled by Photoredox/Ni Dual-Catalyzed Cross-Coupling.
Article in The Journal of organic chemistry, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
11 citing papers in PubMed.
- A unified strategy for α-alkoxyalkyl radical generationOrganic chemistry frontiers : an international journal of organic chemistry · 2026Article
- Aldehyde-Olefin Couplings Via Sulfoxylate-Mediated Oxidative Generation of Ketyl Radical Anions.Journal of the American Chemical Society · 2024Article
- Variable structure diversification by multicatalysis: the case of alcohols.Chemical communications (Cambridge, England) · 2023Review
- Direct Synthesis of α-Aryl-α-Trifluoromethyl Alcohols via Nickel Catalyzed Cross-Electrophile Coupling.Angewandte Chemie (International ed. in English) · 2022Article
- Metallaphotoredox: The Merger of Photoredox and Transition Metal Catalysis.Chemical reviews · 2022Review
- Photons or Electrons? A Critical Comparison of Electrochemistry and Photoredox Catalysis for Organic Synthesis.Chemical reviews · 2022Review
- Stereochemistry of Transition Metal Complexes Controlled by the Metallo-Anomeric Effect.Journal of the American Chemical Society · 2020Article
- β-Silyloxy Allylboronate Esters through an Aldehyde Borylation/Homologation Sequence.Tetrahedron letters · 2020Article
- Radical coupling ofGreen synthesis and catalysis · 2020Article
- Alkyl Carbon-Carbon Bond Formation by Nickel/Photoredox Cross-Coupling.Angewandte Chemie (International ed. in English) · 2019Review
- Selective Hydrogen Atom Abstraction through Induced Bond Polarization: Direct α-Arylation of Alcohols through Photoredox, HAT, and Nickel Catalysis.Angewandte Chemie (International ed. in English) · 2018Article
Corrections and comments
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Authors and funding
2 authors.
Funding
Abstract
An operationally simple, mild, redox-neutral method for the cross-coupling of α-hydroxyalkyltrifluoroborates is reported. Utilizing an Ir photocatalyst, α-hydroxyalkyl radicals are generated from the single-electron oxidation of the trifluoroborates, and these radicals are subsequently engaged in a nickel-catalyzed C-C bond-forming reaction with aryl halides. The process is highly selective, functional group tolerant, and step economical, which allows the direct synthesis of secondary benzylic alcohol motifs.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.