ArticleNature chemistry2017
Enantioselective cyclizations and cyclization cascades of samarium ketyl radicals.
Article in Nature chemistry, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 41 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
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Who cites it
41 citing papers in PubMed, 128 citations in OpenAlex.
- Photodriven Sm-Catalyzed Asymmetric Ketyl-Olefin Coupling.Journal of the American Chemical Society · 2026Article
- Contemporary Strategies in SmIAngewandte Chemie (International ed. in English) · 2025Review
- Enantioselective Radical Dearomative Conjugate Amination Enabled by Co(II)-Based Metalloradical Catalysis.Nature catalysis · 2025Article
- Asymmetric C-H Amination via Fe(III)-Metalloradical Catalysis Featuring α-Fe(IV)-Aminyl Radicals as Key Intermediates.Journal of the American Chemical Society · 2025Article
- Catalytic Metalloradical System for Radical 1,6-C(spJournal of the American Chemical Society · 2025Article
- Photodriven Sm(III)-to-Sm(II) Reduction for Catalytic Applications.Journal of the American Chemical Society · 2024Article
- Synthesis of alcohols: streamlined C1 to CChemical science · 2024Article
- A blueprint for catalysis.Nature chemistry · 2024Article
- Article
- Hydroxyl-Directed Regio- and Diastereoselective Allylic Sulfone Reductions with [Sm(HThe Journal of organic chemistry · 2024Article
- Iron(III)-based metalloradical catalysis for asymmetric cyclopropanation via a stepwise radical mechanism.Nature chemistry · 2023Article
- Radical Group Transfer of Vinyl and Alkynyl Silanes Driven by Photoredox Catalysis.The Journal of organic chemistry · 2023Article
- Enantioselective radical cascade cyclization via Ti-catalyzed redox relay.Tetrahedron letters · 2023Article
- Asymmetric Radical Bicyclization for Stereoselective Construction of Tricyclic Chromanones and Chromanes with Fused Cyclopropanes.Journal of the American Chemical Society · 2023Article
- Cooperative Intrinsic Basicity and Hydrogen Bonding Render SmIACS omega · 2022Article
- Diastereoselective Radical 1,4-Ester Migration: Radical Cyclizations of Acyclic Esters with SmIJournal of the American Chemical Society · 2022Article
- Solid-state and solution-phase characterization of SmDalton transactions (Cambridge, England : 2003) · 2022Article
- Combined radical and ionic approach for the enantioselective synthesis of β-functionalized amines from alcohols.Nature synthesis · 2022Article
- Radical differentiation of two ester groups in unsymmetrical diazomalonates for highly asymmetric olefin cyclopropanation.Chem catalysis · 2022Article
- Metalloradical Activation of In Situ-Generated α-Alkynyldiazomethanes for Asymmetric Radical Cyclopropanation of Alkenes.Journal of the American Chemical Society · 2022Article
Corrections and comments
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Authors and funding
4 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The rapid generation of molecular complexity from simple starting materials is a key challenge in synthesis. Enantioselective radical cyclization cascades have the potential to deliver complex, densely packed, polycyclic architectures, with control of three-dimensional shape, in one step. Unfortunately, carrying out reactions with radicals in an enantiocontrolled fashion remains challenging due to their high reactivity. This is particularly the case for reactions of radicals generated using the classical reagent, SmI
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.