ArticleAngewandte Chemie (International ed. in English)2018
Alkene 1,2-Difunctionalization by Radical Alkenyl Migration.
Article in Angewandte Chemie (International ed. in English), 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 31 papers.
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Who cites it
31 citing papers in PubMed.
- Halogen bonding-induced 1,3-carbohydroxylation of allyl carboxylatesChemical science · 2026Article
- Regio-reversed alkenyl-arylation of ynamidesChemical science · 2026Article
- EDA Complex-Driven Desaturation of Heterocyclic Carbonyl Compounds Enabled by HFIP.Angewandte Chemie (International ed. in English) · 2025Article
- Remote difunctionalization of alkenes through a photocatalytically triggered radical clock and α-carbonyl carbocation generation.Communications chemistry · 2025Article
- Enhancing Electron Donor-Acceptor Complex Photoactivation with a Stable Perylene Diimide Metal-Organic Framework.Journal of the American Chemical Society · 2025Article
- Defluorinative Cyclization of Enamides with Fluoroalkyl Halides Through Two Vicinal C(spAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Ni-Catalyzed Regioselective Alkylarylation of Unactivated Alkenes in Amines Enabled by Cooperative Ligand Effects of Nitriles and Electron-Deficient Alkenes.Journal of the American Chemical Society · 2025Article
- NIR-II emissive anionic copper nanoclusters with intrinsic photoredox activity in single-electron transfer.Nature communications · 2024Article
- Arylcarboxylation of unactivated alkenes with CONature communications · 2023Article
- Shining light on halogen-bonding complexes: a catalyst-free activation mode of carbon-halogen bonds for the generation of carbon-centered radicals.Chemical science · 2023Review
- Expanding Reaction Profile of Allyl Carboxylates via 1,2-Radical Migration (RaM): Visible-Light-Induced Phosphine-Catalyzed 1,3-Carbobromination of Allyl Carboxylates.Journal of the American Chemical Society · 2023Article
- Intramolecular trapping of spiro radicals to produce unusual cyclization products from usual migration substrates.Chemical science · 2023Article
- Activation of perfluoroalkyl iodides by anions: extending the scope of halogen bond activation to C(spChemical science · 2023Article
- Visible light-initiated radical 1,3-difunctionalization of β,γ-unsaturated ketones.Science advances · 2022Article
- Photocatalytic C(spChemical science · 2022Review
- Catalytic electron drives host-guest recognition.Chemical science · 2022Article
- Aryl Transfer Strategies Mediated by Photoinduced Electron Transfer.Chemical reviews · 2022Review
- Palladium-Catalyzed Cascade Carbonylation to α,β-Unsaturated Piperidones via Selective Cleavage of Carbon-Carbon Triple Bonds.Angewandte Chemie (International ed. in English) · 2021Article
- Intramolecular Hydrogen Atom Transfer Induced 1,2-Migration of Boronate Complexes.Organic letters · 2021Article
- Recent advances in the chemistry of ketyl radicals.Chemical Society reviews · 2021Article
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Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Transition-metal-free radical α-perfluoroalkylation with the accompanying vicinal β-alkenylation of unactivated alkenes is presented. These radical cascades proceed by means of 1,4- or 1,5-alkenyl migration by electron catalysis on readily accessed allylic alcohols. The reactions comprise a regioselective perfluoroalkyl radical addition with subsequent alkenyl migration and concomitant deprotonation to generate a ketyl radical anion that sustains the chain as a single-electron-transfer reducing reagent.
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.