ArticleChemical science2017
A complementary pair of enantioselective switchable organocatalysts.
Article in Chemical science, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
10 citing papers in PubMed.
- Switchable supramolecular helices for asymmetric stereodivergent catalysis.Nature communications · 2024Article
- From Organic Fragments to Photoswitchable Catalysts: The OFF-ON Structural Repository for Transferable Kernel-Based Potentials.Journal of chemical information and modeling · 2024Article
- How Robust Is the Reversible Steric Shielding Strategy for Photoswitchable Organocatalysts?The Journal of organic chemistry · 2022Article
- Cyclization of interlocked fumaramides into β-lactams: experimental and computational mechanistic assessment of the key intercomponent proton transfer and the stereocontrolling active pocket.Chemical science · 2020Article
- Light-Modulated Self-Blockage of a Urea Binding Site in a Stiff-Stilbene Based Anion Receptor.Chemphyschem : a European journal of chemical physics and physical chemistry · 2019Article
- Dissipative Catalysis with a Molecular Machine.Angewandte Chemie (International ed. in English) · 2019Article
- Central-to-Helical-to-Axial-to-Central Transfer of Chirality with a Photoresponsive Catalyst.Journal of the American Chemical Society · 2018Article
- New molecular switch architectures.Proceedings of the National Academy of Sciences of the United States of America · 2018Article
- Simultaneous complementary photoswitching of hemithioindigo tweezers for dynamic guest relocalization.Nature communications · 2018Article
- Spectroscopic Study of aACS omega · 2018Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
A pair of enantioselective switchable bifunctional catalysts are shown to promote a range of conjugate addition reactions in up to 95 : 5 e.r. and 95% conversion. Each catalyst can be switched OFF using conditions that switch the other catalyst ON. Catalyst ON : OFF ratios of up to 98 : 2 and 1 : 99 were achieved, with a ratio of reaction rates of up to 16 : 1 between the ON and OFF states, maintained over complete ON-OFF-ON and OFF-ON-OFF cycles. However, simultaneous operation of the catalyst pair in the same reaction vessel, which in principle could allow product handedness to be switched by simple
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.