ArticleChemical science2017
Ketones as directing groups in photocatalytic sp
Article in Chemical science, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
14 citing papers in PubMed.
- Regioselective Synthesis of Methyl Enol Ethers from Cycloalkanones via O-Methylation of Kinetic Enolates.Synthesis · 2026Article
- Fluorinated terpenoids and their fluorine-containing derivatives.RSC advances · 2026Review
- The Fluorinative Skeletal Rearrangement of Lumisantonin: An Unanticipated Dual Role of Selectfluor.The Journal of organic chemistry · 2025Article
- Protodefluorinated SelectfluorChemSusChem · 2024Article
- Kinetically controlled synthesis of rotaxane geometric isomers.Chemical science · 2024Article
- Benzoates as photosensitization catalysts and auxiliaries in efficient, practical, light-powered direct C(spChemical science · 2022Article
- Hydroxy-directed fluorination of remote unactivated C(spChemical science · 2022Article
- Total Synthesis and Computational Investigations of Sesquiterpene-Tropolones Ameliorate Stereochemical Inconsistencies and Resolve an Ambiguous Biosynthetic Relationship.Journal of the American Chemical Society · 2021Article
- Kinetics of Electrophilic Fluorination of Steroids and Epimerisation of Fluorosteroids.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Photosensitized direct C-H fluorination and trifluoromethylation in organic synthesis.Beilstein journal of organic chemistry · 2020Review
- N-Directed fluorination of unactivated CspChemical science · 2019Article
- Visible light-induced direct α C-H functionalization of alcohols.Nature communications · 2019Article
- Photoinduced Remote Functionalization of Amides and Amines Using Electrophilic Nitrogen Radicals.Angewandte Chemie (International ed. in English) · 2018Article
- Photoinduced Remote Functionalisations by Iminyl Radical Promoted C-C and C-H Bond Cleavage Cascades.Angewandte Chemie (International ed. in English) · 2018Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The ubiquitous ketone carbonyl group generally deactivates substrates toward radical-based fluorinations, especially sites closest to it. Herein, ketones are used instead to direct aliphatic fluorination using Selectfluor, catalytic benzil, and visible light. Selective β- and γ-fluorination are demonstrated on rigid mono-, di-, tri-, and tetracyclic (steroidal) substrates employing both cyclic and exocyclic aliphatic ketones as directing groups.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.